VBr 3 is a van der Waals antiferromagnet below the Néel temperature of 26.5 K with a saturation moment of 1.2 µ B /f.u. above the metamagnetic transitions detected in the in-plane and out-of-plane directions. To reveal the AFM structure of VBr 3 experimentally, we performed a single-crystal neutron diffraction study on a large highquality crystal. The collected data confirmed a slight monoclinic distortion of the high-temperature rhombohedral structure below 90 K. The magnetic structure was, nevertheless, investigated within the R-3 model. The antiferromagnetic structure propagation vector k = (1, 0, ½) was revealed. In an attempt to determine the magnetic structure, 72 non-equivalent magnetic reflections were recorded. The experimental data were confronted with the magnetic space groups dictated by the R-3 lattice symmetry and propagation vector. The best agreement between the experimental data and the magnetic structure model was obtained for the space group P-1.1′_c. The magnetic unit cell of the proposed unique antiferromagnetic structure with periodicity 6c is built from two identical triple layers antiferromagnetically coupled along the c axis. Each triple layer comprises a Néel antiferromagnetic monolayer sandwiched between two antiferromagnetically coupled ferromagnetic monolayers.