Article Dans Une Revue Beilstein Journal of Organic Chemistry Année : 2024

Phenylseleno trifluoromethoxylation of alkenes

Résumé

Trifluoromethoxylated molecules and selenylated compounds find a wide range of interesting applications, but separately. In order to combine the potential of these two motifs and to propose a new class of compounds, we have developed an electrophilic phenylseleno trifluoromethoxylation of alkenes, which leads to β-selenylated trifluoromethoxylated compounds or, upon subsequent reduction, to the trifluoromethoxylated ones.

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hal-04711420 , version 1 (27-09-2024)

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Clément Delobel, Armen Panossian, Gilles Hanquet, Frédéric R Leroux, Fabien Toulgoat, et al.. Phenylseleno trifluoromethoxylation of alkenes. Beilstein Journal of Organic Chemistry, 2024, 20, pp.2434-2441. ⟨10.3762/bjoc.20.207⟩. ⟨hal-04711420⟩
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