In recent years, the estimation of biometric parameters from facial visuals, including images and videos, has emerged as a prominent area of research. However, the robustness of deep learning-based models is challenged, particularly in the presence of changing illumination conditions. To overcome these limitations and unlock new opportunities, thermal imagery has arisen as a viable alternative. Nevertheless, the limited availability of databases containing thermal data and the small amount of annotations on them limits the exploration of this spectrum. Motivated by this gap, this paper introduces the Label-EURECOM Visible and Thermal (LVT) Face Database for face biometrics. This pioneering database includes paired visible and thermal images and videos from 52 subjects along with metadata of 22 soft biometrics and health parameters. Due to the reduced number of existing databases in this domain, the LVT Face Database aims to facilitate further research and advancements in the utilization of thermal imagery for diverse eHealth applications and soft biometric estimation. Moreover, we present the first comparative study between visible and thermal spectra as input images for soft biometric estimation, namely gender age and weight, from face images on our collected database.