Post-metallation functionalization of the [(C^C)Au(P^P)]+ scaffold through a hydrothiolation reaction
Résumé
Complex 1 [(C^C)Au(dppv)]PF6 (dppv = cis-1,2-diphenylphosphinoethylene) is reported to react efficiently and selectively with aliphatic and aromatic thiols in the presence of a base. This methodology enables the smooth introduction...