Article Dans Une Revue Dalton Transactions Année : 2024

A stable and true-blue emissive hexacoordinate Si(IV) N-heterocyclic carbene complex and its use in organic light-emitting diodes

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A neutral hexacoordinate Si(IV) complex containing two tridentate N-heterocyclic carbene ligands is synthesised and characterized by X-ray crystallography, optical spectroscopy, electrochemistry and computational methods. The stable compound exhibits remarkable deep-blue photoluminescence particularly in the solid state, which enables its use as an electroluminescent material in organic light-emitting diodes

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hal-04700770 , version 1 (17-09-2024)

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Thibault Thierry, Valerio Giuso, Federico Polo, Pierluigi Mercandelli, Yi-Ting Chen, et al.. A stable and true-blue emissive hexacoordinate Si(IV) N-heterocyclic carbene complex and its use in organic light-emitting diodes. Dalton Transactions, 2024, 53 (14), pp.6445-6450. ⟨10.1039/D4DT00420E⟩. ⟨hal-04700770⟩
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