Difunctionalization Processes Enabled by Hexafluoroisopropanol - Archive ouverte HAL
Article Dans Une Revue ACS Organic & Inorganic Au Année : 2024

Difunctionalization Processes Enabled by Hexafluoroisopropanol

Résumé

In the past 5 years, hexafluoroisopropanol (HFIP) has been used as a unique solvent or additive to enable challenging transformations through substrate activation and stabilization of reactive intermediates. In this Review, we aim at describing difunctionalization processes which were unlocked when HFIP was involved. Specifically, we focus on cyclizations and additions to alkenes, alkynes, epoxides, and carbonyls that introduce a wide range of functional groups of interest.

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hal-04699538 , version 1 (16-09-2024)

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Maciej Piejko, Joseph Moran, David Lebœuf. Difunctionalization Processes Enabled by Hexafluoroisopropanol. ACS Organic & Inorganic Au, 2024, 4 (3), pp.287-300. ⟨10.1021/acsorginorgau.3c00067⟩. ⟨hal-04699538⟩
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