Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2024

Deep Study of Thiocarbamoyl Fluorides: Synthesis and Properties

Résumé

Abstract Thiocarbamoyl fluoride is an understudied fluorinated group, mainly due to the paucity of data on its properties. Herein, an in‐depth study of the stability of thiocarbamoyl fluorides, especially under near‐physiological conditions, is described. Since efficient and easy to implement syntheses of these compounds are still under‐described, a new method, based on the use of a trifluoromethanesulfenamide, a well‐described reagent, has also been developed. This trifluoromethanesulfenamide turned out to be able to generate in situ difluorothiophosgene, which was able to react rapidly with amines to provide various thiocarbamoyl fluorides.

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hal-04684868 , version 1 (03-09-2024)

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Clément Delobel, Emmanuel Chefdeville, Fabien Toulgoat, Thierry Billard. Deep Study of Thiocarbamoyl Fluorides: Synthesis and Properties. Advanced Synthesis and Catalysis, 2024, 366 (16), pp.3474-3480. ⟨10.1002/adsc.202400412⟩. ⟨hal-04684868⟩
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