Article Dans Une Revue Chemistry - A European Journal Année : 2024

Photoresponsive Dioxazaborocanes-Containing Oligomers

Résumé

he synthetic methodology for the preparation of photoresponsive dioxazaborocanes-containing oligomers is developed. It relies on the transformation of the (diisopropylamino)boryl group (-BH(NiPr2)) into a dioxazaborocane unit in the presence β-aminodiols and involves a bis-borylated dithienylethene photochromic unit. The photophysical properties of the obtained oligomers are evaluated as well as their processability for the preparation of spin-coated films. The photomechanical behavior of the resulting films is assessed via displacement tracking profile.

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hal-04684369 , version 1 (10-09-2024)

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Nour Nour Eddine, Laurine Meslong, Marie Cordier, Ismael Arroyo Diaz, Stéphane Aloïse, et al.. Photoresponsive Dioxazaborocanes-Containing Oligomers. Chemistry - A European Journal, 2024, pp.e202402912. ⟨10.1002/chem.202402912⟩. ⟨hal-04684369⟩
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