Fluoride-Catalyzed Cross-Coupling of Silylamides to CF3 -Acrylates: Access to Highly Functionalized Trifluoromethylated and Quaternary Fluorinated Molecular Architectures - Archive ouverte HAL
Article Dans Une Revue Organic Letters Année : 2024

Fluoride-Catalyzed Cross-Coupling of Silylamides to CF3 -Acrylates: Access to Highly Functionalized Trifluoromethylated and Quaternary Fluorinated Molecular Architectures

Résumé

A direct and simple catalytic coupling of non-fluorinated and fluorinated silylbutenamides with-CF3 -unsaturated esters mediated by fluoride ion was carried out. The transformation proceeded with excellent yields to afford new highly-functionalized trifluoromethylated and quaternary fluorinated products.
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Dates et versions

hal-04681405 , version 1 (29-08-2024)

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Samir Bouzbouz. Fluoride-Catalyzed Cross-Coupling of Silylamides to CF3 -Acrylates: Access to Highly Functionalized Trifluoromethylated and Quaternary Fluorinated Molecular Architectures. Organic Letters, 2024, 26 (29), pp.6130-6135. ⟨10.1021/acs.orglett.4c01895⟩. ⟨hal-04681405⟩
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