Article Dans Une Revue Dalton Transactions Année : 2024

Bis(diiminate)-based boron difluoro complexes: effective synthon for bis(borenium) cations

Résumé

A series of boron difluoro bis(diiminate) complexes have been prepared and used to obtain triflate substituted fluoroborane complexes. The corresponding well-defined bis(borenium) cations were subsequently synthesized and structurally authenticated. We are also presenting the first experimental and theoretical study of bis(borenium) cations that are derivative of cationic borinic acid.

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hal-04675235 , version 1 (22-08-2024)

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Darakshan Parveen, Rahul Kumar Yadav, Bijan Mondal, Marie Dallon, Yann Sarazin, et al.. Bis(diiminate)-based boron difluoro complexes: effective synthon for bis(borenium) cations. Dalton Transactions, 2024, 53 (34), pp.14139-14143. ⟨10.1039/D4DT02050B⟩. ⟨hal-04675235⟩
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