Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2024

Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds

Résumé

Abstract We report herein a general one‐pot perfluoroalkylation/dehydrohalogenation protocol for the selective perfluoroalkenylation of silyl dienol ethers in their γ position. Importantly, this methodology is applicable to the synthesis of a wide range of γ‐perfluoroalkenylated enals, enones and α,β‐unsaturated amides. Various perfluoroalkenyl moieties could be efficiently introduced, with an important impact on the E / Z diatereoselectivity of the newly formed fluorinated double bond.

Domaines

Fichier non déposé

Dates et versions

hal-04665645 , version 1 (31-07-2024)

Identifiants

Citer

Marina Briand, Emmanuel Magnier, Elsa Anselmi, Guillaume Dagousset. Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400462⟩. ⟨hal-04665645⟩
62 Consultations
0 Téléchargements

Altmetric

Partager

  • More