Calcium, Strontium and Barium Complexes in Organic Synthesis
Résumé
In the space of 20 years, molecular complexes of the large alkaline earths calcium, strontium and barium have gone from being mere oddities to some of the most exciting catalysts in the landscape of homogenous metal-mediated catalysis. This article reviews the main achievements in the area of organic transformations catalyzed by alkaline-earth complexes. It encompasses a broad range of hydrofunctionalization reactions (e.g., hydroamination, hydrophosphination and hydrogenation) and dehydrocouplings, as well as a range of other reactions that do not fit into any specific category. A survey of the sophisticated processes catalyzed by alkaline-earth Lewis acids is included.
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OMC4_YannSarazin_Alkaline-earth_catalysis_HAL.pdf (6.51 Mo)
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