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Article Dans Une Revue Molecules Année : 2024

4-Vinyl Guaiacol: A Key Intermediate for Biobased Polymers

Résumé

In order to contribute to the shift from petro-based chemistry to biobased chemistry, necessary to minimize the environmental impacts of the chemical industry, 2-methoxy-4-vinylphenol (4-vinyl guaiacol, 4VG) was used to synthesize a platform of biobased monomers. Thus, nine biobased monomers were successfully prepared. The synthesis procedures were investigated through the green metrics calculations in order to quantify the sustainability of our approaches. Their radical homopolymerization in toluene solution initiated by 2,2′-azobis(2-methylpropionitrile) (AIBN) was studied and the effect of residual 4VG as a radical inhibitor on the kinetics of polymerization was also explored. The new homopolymers were characterized by proton nuclear magnetic resonance ($^1$H-NMR) spectroscopy, size exclusion chromatography and thermal analyses (dynamical scanning calorimetry DSC, thermal gravimetric analysis TGA). By varying the length of the alkyl ester or ether group of the 4VG derivatives, homopolymers with T$_g$ ranging from 117°C down to 5°C were obtained. These new biobased monomers could be implemented in radical copolymerization as substitutes to petro-based monomers to decrease the carbon footprint of the resulting copolymers for various applications.

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Dates et versions

hal-04588339 , version 1 (26-05-2024)

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Elena Rigo, Cédric Totée, Vincent Ladmiral, Sylvain Caillol, Patrick Lacroix-Desmazes. 4-Vinyl Guaiacol: A Key Intermediate for Biobased Polymers. Molecules, 2024, 29 (11), pp.2507. ⟨10.3390/molecules29112507⟩. ⟨hal-04588339⟩
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