Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna - Archive ouverte HAL
Article Dans Une Revue Dalton Transactions Année : 2024

Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna

Résumé

A ruthenium nitrosyl complex of formula [Ru$^{II}$(fluorene(C6)CH$_2$O-terpy)(bipy)(NO)]$^{3+}$ (AC) in which fluorene(C6) is the 9,9-dihexylfluorene, terpy the 2,2’;6’,2’’-terpyridine, and bipy the 2,2’-bipyridine is presented with its related [Ru$^{II}$(MeO-terpy)(bipy)(NO)]$^{3+}$ (C) and 9,9-dihexylfluorene 2-hydroxymethylfluorene (A) building blocks. The reference complex C undergoes NO release capabilities under irradiations at λ = 365 nm. The effect of the introduction of the fluorescent A antenna within the resulting AC complex is discussed both experimentally and theoretically. The importance of the encaging parameter defined as Φ$_{AC}$ x I$_{AC}$, in which I$_{AC}$ is the quantity of light absorbed by AC and Φ$_{AC}$ the quantum yield of NO release is evidenced and found concentration dependent. The conditions of optimization of the antenna approach to maximize Φ$_{AC}$ x I$_{AC}$ are discussed. The crystal structure of [Ru$^{II}$(fluorene(C6)CH$_2$O-terpy)(bipy)(NO$_2$)](PF6) last intermediate in the synthesis of AC is also presented.
Fichier principal
Vignette du fichier
Mudrak, Ruthenium nitrosyl complexes, 2024.pdf (3.54 Mo) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Licence

Dates et versions

hal-04580926 , version 1 (21-05-2024)

Licence

Identifiants

Citer

Vladyslav Mudrak, Pascal G. Lacroix, Marine Tassé, Sonia Mallet-Ladeira, Alexander D Roshal, et al.. Ruthenium nitrosyl complexes with NO release capability: the use of fluorene as an antenna. Dalton Transactions, 2024, 53 (23), pp.9777-9791. ⟨10.1039/d4dt01154f⟩. ⟨hal-04580926⟩
86 Consultations
32 Téléchargements

Altmetric

Partager

More