This paper presents a modelling procedure to take into account the capacitive effect at high frequencies, in Eddy Current Non-Destructive Characterization (EC-NDC) of Unidirectional Carbon Fiber Reinforcement Composite (UD-CFRC) rods. To simulate the complete EC-NDC systems, first, the multilayer circular air coil is physically modeled by a finite element (FE) axisymmetric eddy current model coupled to equivalent RL circuit. Each layer of the coil is represented by an equivalent resistance (R) in series with the equivalent inductance (L). Secondly, R and L of the coil layers are computed for several frequencies up to 5Mhz, and then introduced into the equivalent RLC circuit with considering inter-turn and interlayer capacitances. Then the inversion problem is solved in order to identify all inner capacitances of the coil. Finally, the UD-CFRC rod is introduced into the FE eddy current axisymmetric model coupled to an equivalent RLC circuit, as a homogenized conductive material with an equivalent transverse conductivity. The coil with the presence of the homogenized UD-CFRC rod is then modeled as a transformer with a secondary connected to a capacitor in parallel with a resistance in order to evaluate the inner capacitor of the UD-CFRC. All evaluated parameters are then introduced in the last model. The comparison between the computed impedance parts and the measured ones shows a mean error less than 2% and a maximum one of 5% according to the frequency.