Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2022

Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges

David King
  • Fonction : Auteur
Benjamin Atkinson
Lucile Chatelain
Matthew Gregson
  • Fonction : Auteur
John Seed
Ashley Wooles
  • Fonction : Auteur
Nikolas Kaltsoyannis
Stephen Liddle

Résumé

Sequential reduction of a uranium-azide through all the nitride steps is revealed. Experimentally determined U–U coupling in the diuranium( iv )–dinitride is shown by ab initio calculations to stem from the nitride bridges, not U–U bonding.

Domaines

Chimie

Dates et versions

hal-04568631 , version 1 (05-05-2024)

Identifiants

Citer

David King, Benjamin Atkinson, Lucile Chatelain, Matthew Gregson, John Seed, et al.. Uranium–nitride chemistry: uranium–uranium electronic communication mediated by nitride bridges. Dalton Transactions, 2022, 51 (22), pp.8855-8864. ⟨10.1039/D2DT00998F⟩. ⟨hal-04568631⟩
23 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More