Facile N-functionalization and strong magnetic communication in a diuranium( v ) bis-nitride complex - Archive ouverte HAL
Article Dans Une Revue Chemical Science Année : 2019

Facile N-functionalization and strong magnetic communication in a diuranium( v ) bis-nitride complex

Luciano Barluzzi
  • Fonction : Auteur
Farzaneh Fadaei-Tirani
Ivica Zivkovic
Marinella Mazzanti

Résumé

A diuranium( v ) bis-nitride complex supported by siloxide ligands displays remarkable reactivity in ambient conditions with small molecules such as CS 2 , CO 2 , CO and H 2 resulting in N–C and N–H bond formation. The nitride linker also leads to an unusually strong antiferromagnetic coupling between uranium( v ) ions.

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Chimie

Dates et versions

hal-04568628 , version 1 (05-05-2024)

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Citer

Luciano Barluzzi, Lucile Chatelain, Farzaneh Fadaei-Tirani, Ivica Zivkovic, Marinella Mazzanti. Facile N-functionalization and strong magnetic communication in a diuranium( v ) bis-nitride complex. Chemical Science, 2019, 10 (12), pp.3543-3555. ⟨10.1039/C8SC05721D⟩. ⟨hal-04568628⟩
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