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Article Dans Une Revue European Journal of Organic Chemistry Année : 2024

One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals

Résumé

Abstract We describe herein the direct electrophilic γ‐trifluoromethylthiolation and γ‐methylthiolation of enals, via the in situ formation of the corresponding silyl dienol ether. This one‐pot process is carried out under simple and mild reaction conditions and is compatible with a variety of functional groups.

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Chimie
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Dates et versions

hal-04533535 , version 1 (05-04-2024)

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Camille Banoun, Killian Henault, Emmanuel Magnier, Guillaume Dagousset. One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202400119⟩. ⟨hal-04533535⟩
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