Line shapes of isotropic and depolarized CILS spectra of neon: Interaction potential and pair polarizability
Formes des spectres CILS isotrope et dépolarisé du néon : Potentiel d'interaction et polarisabilité de paire
Résumé
The present work proposes three interaction potentials between two gaseous neon atoms and applies them
to the study of models representing the anisotropy and trace of the induced pair polarizability tensor. The
proposed empirical interatomic potentials for the gaseous Ne-Ne interaction are developed by fitting the
Improved Lennard-Jones (ILJ), Modified Tang-Toennies (MTT) and Barker et al. (BFW) potentials simulta-
neously to the spectroscopic and transport properties over a wide temperature range. The validity of the
proposed interatomic potentials is verified by comparing the calculated and experimental second pressure
virial coefficient over a wide temperature range. In addition to this, the results show satisfactory accordance
between the experimental and calculated vibrational energy levels using the deduced pair potential parameters
compared to those reported for neon gas. These comparisons exhibit acceptable accuracy when the present
work potential parameters are inserted to reproduce the transport and thermo-physical properties, besides the
spectral moments and the spectral line-shape intensities for neon gas. The isotropic and depolarized collision-
induced light scattering (CILS) spectra are produced and analyzed as functions of the potential considered. They
exhibit sensitivity to both the attractive part of the potential and the short-range values of the polarizability
anisotropy or mean at intermediate and high frequencies. Mean and anisotropy are deduced directly from
spectral line shapes using a new inversion method.