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Article Dans Une Revue Dalton Transactions Année : 2024

Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis

Résumé

The synthesis of ruthenium-complexes with cyclic (amino)(barrelene)carbenes (namely CABCs) as ligands is reported. Isolated in moderate to good yields, these new complexes showed impressive thermal stability at 110 °C over several days. Good catalytic performances were demonstrated in various ring-closing metathesis (RCM), macrocyclic-RCM, ring-closing enyne metathesis (RCEYM), cross-metathesis (CM), and ring-opening cross metathesis (ROCM) reactions.

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Chimie
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hal-04513138 , version 1 (20-03-2024)

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Paternité - Pas d'utilisation commerciale

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Jakub Talcik, Melinda R Serrato, Antonio del Vecchio, Sophie Colombel-Rouen, Jennifer Morvan, et al.. Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis. Dalton Transactions, 2024, Dalton Transactions (cambridge, England : 2003), 53 (12), pp.5346-5350. ⟨10.1039/d4dt00102h⟩. ⟨hal-04513138⟩
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