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Chapitre D'ouvrage Année : 2023

Fatty Acid-Based Polycarbonates Synthesis and Crosslinking Through the Malonate Route

Résumé

In this study, a series of fatty acid-based 6-member cyclic carbonates, 6CCs, were synthesized through the malonate route and the conditions to their copolymerization with trimethylene carbonate (TMC) optimized. These functional aliphatic polycarbonates were fully characterized and the influence of several parameters on the polymer properties investigated. Finally, preliminary experiments of the derivation and crosslinking of these polycarbonates were carried out.

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hal-04495245 , version 1 (08-03-2024)

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Pierre-Luc Durand, Cédric Le Coz, Étienne Grau, Henri Cramail. Fatty Acid-Based Polycarbonates Synthesis and Crosslinking Through the Malonate Route. H. N. Cheng; Richard A. Gross. Sustainable Green Chemistry in Polymer Research. Volume 1. Biocatalysis and Biobased Materials, 1450, American Chemical Society, pp.119-144, 2023, ACS Symposium Series, ⟨10.1021/bk-2023-1450.ch008⟩. ⟨hal-04495245⟩

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