<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04471705</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-08T12:23:31+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">High temperature oxidation of HEAs and MC-strengthened HEAs in presence of water vapor</title>
            <author role="aut">
              <persName>
                <forename type="first">Patrice</forename>
                <surname>Berthod</surname>
              </persName>
              <email type="md5">b30e82c3308f5b734113e6674b019263</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">patrice-berthod</idno>
              <idno type="idhal" notation="numeric">172355</idno>
              <idno type="halauthorid" notation="string">29244-172355</idno>
              <idno type="IDREF">https://www.idref.fr/152895035</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-8035-927X</idno>
              <affiliation ref="#struct-104710"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Lionel</forename>
                <surname>Aranda</surname>
              </persName>
              <email type="md5">b74c9001a12fecc46fea1f6411c92ca8</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="string">lionelaranda</idno>
              <idno type="idhal" notation="numeric">1090683</idno>
              <idno type="halauthorid" notation="string">745340-1090683</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0428-2397</idno>
              <affiliation ref="#struct-104710"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Ghouti</forename>
                <surname>Medjahdi</surname>
              </persName>
              <email type="md5">64c8469fe3da93dbb9c7a8d783e34c63</email>
              <email type="domain">univ-lorraine.fr</email>
              <idno type="idhal" notation="numeric">1118149</idno>
              <idno type="halauthorid" notation="string">427651-1118149</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3968-3473</idno>
              <affiliation ref="#struct-104710"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Patrice</forename>
                <surname>BERTHOD</surname>
              </persName>
              <email type="md5">b30e82c3308f5b734113e6674b019263</email>
              <email type="domain">univ-lorraine.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2024-02-21 17:53:58</date>
              <date type="whenModified">2025-11-04 14:40:40</date>
              <date type="whenReleased">2024-02-22 08:20:38</date>
              <date type="whenProduced">2024-03-03</date>
              <date type="whenEndEmbargoed">2024-02-21</date>
              <ref type="file" target="https://hal.science/hal-04471705v1/document">
                <date notBefore="2024-02-21"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-04471705v1/file/135%20POSTER%20TMS2024Orlando%20PB%20LA%20GM.pdf" id="file-4471705-3879212">
                <date notBefore="2024-02-21"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="682003">
                <persName>
                  <forename>Patrice</forename>
                  <surname>BERTHOD</surname>
                </persName>
                <email type="md5">b30e82c3308f5b734113e6674b019263</email>
                <email type="domain">univ-lorraine.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04471705</idno>
            <idno type="halUri">https://hal.science/hal-04471705</idno>
            <idno type="halBibtex">berthod:hal-04471705</idno>
            <idno type="halRefHtml">&lt;i&gt;TMS 2024 153rd Annual Meeting &amp; Exhibition&lt;/i&gt;, Mar 2024, Orlando, United States</idno>
            <idno type="halRef">TMS 2024 153rd Annual Meeting &amp; Exhibition, Mar 2024, Orlando, United States</idno>
            <availability status="restricted">
              <licence target="https://creativecommons.org/licenses/by-nc-nd/4.0/">CC BY-NC-ND 4.0 - Attribution - Non-commercial use - No Derivative Works<ref corresp="#file-4471705-3879212"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-LORRAINE">Université de Lorraine</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="IJL-UL">Institut Jean Lamour</idno>
            <idno type="stamp" n="IJL-206">IJL - équipe Surface et Interface, Réactivité Chimique des Matériaux</idno>
            <idno type="stamp" n="M4-UL">Pôle scientifique Matière, Matériaux, Métallurgie, Mécanique de l'Université de Lorraine</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="invited" n="0">No</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
            <note type="proceedings" n="0">No</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">High temperature oxidation of HEAs and MC-strengthened HEAs in presence of water vapor</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Patrice</forename>
                    <surname>Berthod</surname>
                  </persName>
                  <email type="md5">b30e82c3308f5b734113e6674b019263</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">patrice-berthod</idno>
                  <idno type="idhal" notation="numeric">172355</idno>
                  <idno type="halauthorid" notation="string">29244-172355</idno>
                  <idno type="IDREF">https://www.idref.fr/152895035</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-8035-927X</idno>
                  <affiliation ref="#struct-104710"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Lionel</forename>
                    <surname>Aranda</surname>
                  </persName>
                  <email type="md5">b74c9001a12fecc46fea1f6411c92ca8</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="string">lionelaranda</idno>
                  <idno type="idhal" notation="numeric">1090683</idno>
                  <idno type="halauthorid" notation="string">745340-1090683</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0428-2397</idno>
                  <affiliation ref="#struct-104710"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Ghouti</forename>
                    <surname>Medjahdi</surname>
                  </persName>
                  <email type="md5">64c8469fe3da93dbb9c7a8d783e34c63</email>
                  <email type="domain">univ-lorraine.fr</email>
                  <idno type="idhal" notation="numeric">1118149</idno>
                  <idno type="halauthorid" notation="string">427651-1118149</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3968-3473</idno>
                  <affiliation ref="#struct-104710"/>
                </author>
              </analytic>
              <monogr>
                <meeting>
                  <title>TMS 2024 153rd Annual Meeting &amp; Exhibition</title>
                  <date type="start">2024-03-03</date>
                  <date type="end">2024-03-07</date>
                  <settlement>Orlando</settlement>
                  <country key="US">United States</country>
                </meeting>
                <respStmt>
                  <resp>conferenceOrganizer</resp>
                  <name>The Minerals, Metals &amp; Materials Society</name>
                </respStmt>
                <imprint/>
              </monogr>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">High Entropy Alloys</term>
                <term xml:lang="en">HEA</term>
                <term xml:lang="en">MC carbides</term>
                <term xml:lang="en">High temperature oxidation</term>
                <term xml:lang="en">Water vapor</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.inor">Chemical Sciences/Inorganic chemistry</classCode>
              <classCode scheme="halDomain" n="chim.mate">Chemical Sciences/Material chemistry</classCode>
              <classCode scheme="halTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halOldTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halTreeTypology" n="POSTER">Poster communications</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Exposed to air at high temperature, chromia-forming alloys, and even alumina-forming alloys, may behave differently in presence of water vapor by comparison to dry air. Notably, chromia volatilization may be accelerated for a given constant temperature and even it may take place at temperatures lower than 1000°C. Usually not really concerned by volatilization, alumina may start to be affected by volatilization in case of humidified air. Due to the presence of manganese in their chemical compositions, Cantor's alloys and derivatives oxidize with the development of complex oxide scalesincluding mixed {Cr,Mn}–oxides, which may behave differently than pure chromia. In this work, oxidation tests in hot humidified air are carried out, followed by kinetic treatment of the mass gain files. Characterization focuses not only on the isothermal mass gain at the stage temperature (1000°C) but attention is also paid to the mass variations during heating and to the ones during cooling. Differences in mass variation behavior will be evidenced and interpreted in term of influence of the presence of water vapor and also in term of effect of the alloy’s chemical composition.The presence of water vapor, with the content tested here, obviously lowered significantly the isothermal mass gain kinetic by oxidation at 1000°C of these {Mn,Cr}–modified Cantor–type cast alloys (but without change of the hierarchy among the carbide–free and the MC–containing alloys). Another beneficial effect is perhaps also to notice, concerning the mass loss during cooling, according to the present kinetic results. This thermogravimetry part of the study of the effect of water vapor on the high temperature oxidation behavior of these alloys will be soon completed with the results of the ongoing post–mortem metallography investigation of their oxidized states. One can hope that these results will explain the present observations.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-104710" status="VALID">
          <idno type="IdRef">152607595</idno>
          <idno type="ISNI">0000000094077201</idno>
          <idno type="RNSR">200918462H</idno>
          <idno type="IdUnivLorraine">[UL]RTA--</idno>
          <idno type="ROR">https://ror.org/05k1smh27</idno>
          <orgName>Institut Jean Lamour</orgName>
          <orgName type="acronym">IJL</orgName>
          <date type="start">2009-01-01</date>
          <desc>
            <address>
              <addrLine>Institut Jean Lamour - CNRS - Université de Lorraine. Campus Artem 2 allée André Guinier BP 50840 54011 Nancy Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://ijl.univ-lorraine.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-341038" type="direct"/>
            <relation active="#struct-413289" type="direct"/>
            <relation name="UMR7198" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-413289" status="VALID">
          <idno type="IdRef">157040569</idno>
          <idno type="IdUnivLorraine">[UL]100--</idno>
          <idno type="ROR">https://ror.org/04vfs2w97</idno>
          <orgName>Université de Lorraine</orgName>
          <orgName type="acronym">UL</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>34 cours Léopold - CS 25233 - 54052 Nancy cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lorraine.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>