Separation, speciation and quantification of both chromium (VI) and chromium (III) in tanned leather samples: a comparative study and validation of analytical methods - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Collagen and Leather Année : 2023

Separation, speciation and quantification of both chromium (VI) and chromium (III) in tanned leather samples: a comparative study and validation of analytical methods

Résumé

Abstract In the present work, a comparative study of analytical methods for the simultaneous and quantitative determination of trivalent and hexavalent chromium is presented. For the analysis by ion chromatography-inductively coupled plasma-mass spectrometry, two different columns were tested, as well as different mobile phases and different pH of the samples. The optimized analytical method permitted the separation of Cr(III) and Cr(VI) using 75 mmol/L NH 4 NO 3 pH 3 as chromatographic eluent. The method was validated and applied to real samples, allowing the determination of both species simultaneously, even when there is a huge difference of concentration between Cr(III) and Cr(VI). Limit of detection and limit of quantification for Cr(III) were found to be 0.016 and 0.054 $$\upmu$$ μ g/L (0.3 and 1.1 $$\upmu$$ μ g/kg), respectively, and for Cr(VI) 0.13 and 0.43 $$\upmu$$ μ g/L (7 and 22 $$\upmu$$ μ g/kg), respectively. Possible species interconversions were monitored through the use of chromium isotopic standards, which confirmed that the optimized methodology preserves chromium speciation during extraction and analysis. Fourier-transform ion cyclotron resonance-mass spectrometry permitted the structure elucidation of the complex formed during ethylenediaminetetraacetic acid extraction. Graphical Abstract

Domaines

Chimie

Dates et versions

hal-04429913 , version 1 (31-01-2024)

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Mónica Gisel Arellano-Sánchez, Juliette Vievard, Lamia Moufarrej, Christine Devouge-Boyer, Marie Hubert-Roux, et al.. Separation, speciation and quantification of both chromium (VI) and chromium (III) in tanned leather samples: a comparative study and validation of analytical methods. Collagen and Leather, 2023, 5 (1), pp.18. ⟨10.1186/s42825-023-00125-7⟩. ⟨hal-04429913⟩
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