Article Dans Une Revue Organic Process Research and Development Année : 2024

Hydrochlorination of Alkenes with Hydrochloric Acid

Résumé

The hydrochlorination of alkenes with hydrogen chloride gas is typically limited to activated olefins. Herein, we present an innovative hydrochlorination approach utilizing hydrochloric acid within vigorously agitated solutions. Notably, the introduction of acetic acid was found to enhance the reaction rate. We substantiated the practicality of our method by conducting the hydrochlorination of styrene on a 1-mol scale with a 96% yield.

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hal-04394987 , version 1 (17-05-2024)

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Arnaud Olivier, Daniel Muller. Hydrochlorination of Alkenes with Hydrochloric Acid. Organic Process Research and Development, 2024, 28 (1), pp.305-309. ⟨10.1021/acs.oprd.3c00418⟩. ⟨hal-04394987⟩
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