In this paper, we focus on the industrial production of porcelain in the Bordeaux area (France) in the 19th century. Our main objective is to assess the evolution of production technology of the same manufactory over a period of more than 40 years. A multi-analytical approach was used to investigate glazes and bodies of thirty-four sherds of biscuit and porcelain found in an archaeological context. The microstructural, chemical, and mineralogical characterization was performed using a combination of scanning electron microscopy, coupled with energy dispersive spectroscopy (SEM-EDS), particles induced X-ray and gamma emission (PIXE-PIGE), and X-ray diffraction (XRD). Results obtained on the characterization of the ceramic production technologies and on the chemical modification over time contributes to investigate this industrial production, which is not well documented by the written archives. The examination of the biscuits, rare artifacts, showed that the porcelain bodies were produced by mixing kaolinitic clays, quartz, and potassium feldspars. The mineralogical analysis of the ceramic supports allowed hypotheses to be put forward on the temperatures of the biscuit firing (around 950 °C) and the second firing (over 1200 °C). Furthermore, the treatment of the compositional data, including both glazes and bodies, using multivariate statistical analysis, revealed different types of production corresponding to the different chronological periods of production at Bordeaux throughout the 19th century. These results will enable us to consider the possibility of authenticating non-stamped and undecorated pieces.