Preparation of powerful exchanged Faujasite zeolite materials used as effective heterogeneous catalyst for photo-Fenton oxidation of methyl orange (MO) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Reaction kinetics, mechanisms and catalysis Année : 2024

Preparation of powerful exchanged Faujasite zeolite materials used as effective heterogeneous catalyst for photo-Fenton oxidation of methyl orange (MO)

Résumé

Novel heterogeneous photo-Fenton catalyst, iron coated Faujasite zeolite (Fe-FAU) was synthesized by exchange-calcination method. Iron was exchanged in zeolite sup- port based on Faujasite type zeolites prepared in laboratory from instratified illitic- kaolinite raw Tunisian clay. The studied materials were characterized by XRD, BET, SEM–EDX and FTIR methods. X-ray diffraction (XRD) analysis showed that the zeolite structure was not affected by the catalyst preparation method. BET results revealed that Fe-FAU possess a trimodal structure (micro, meso and macropores) with a porosity of 0.28 cm3/g. The catalytic performance of the Fe-FAU was stud- ied for the oxidation of methyl orange (MO) in aqueous solution in the presence of hydrogen peroxide. The effects of different operating parameters on the degradation efficiency were studied at atmospheric pressure. The results indicated that the Fe doped zeolite exhibited good degradation efficiency. Measurements of the miner- alization of MO by TOC analysis showed that the maximum degradation of MO (94%) was detected with 50 mg of adsorbent dosage after 20 min of contact time and under UVC irradiation. Moreover, in order to predict the empirical variables signifi- cance, the variances analysis “ANOVA” was used. Response Surface Methodology (RSM) incorporating Central Composite Design (CCD) of experiments was applied to optimize oxidation parameters. High regression (R2 = 0.95) and the low probabil- ity (p value < 0.0001) values signify the validity of the quadratic model to predict the removal (%) of MO.

Domaines

Chimie
Fichier non déposé

Dates et versions

hal-04382568 , version 1 (09-01-2024)

Identifiants

Citer

Olfa Ouled Ltaief, Stéphane Siffert, Mourad Benzina, Sophie Fourmentin. Preparation of powerful exchanged Faujasite zeolite materials used as effective heterogeneous catalyst for photo-Fenton oxidation of methyl orange (MO). Reaction kinetics, mechanisms and catalysis, 2024, 137 (1), pp.547-570. ⟨10.1007/s11144-023-02563-0⟩. ⟨hal-04382568⟩
17 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More