<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04339456</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-14T15:10:02+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Pure and RE 3+ -Doped La7O6 (VO4) 3 (RE = Eu, Sm): Polymorphism Stability and Luminescence Properties of a New Oxyvanadate Matrix</title>
            <author role="aut">
              <persName>
                <forename type="first">María Alejandra</forename>
                <surname>Gómez Torres</surname>
              </persName>
              <idno type="halauthorid">1830856-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Anna</forename>
                <surname>Kaczmarek</surname>
              </persName>
              <idno type="idhal" notation="numeric">1323434</idno>
              <idno type="halauthorid" notation="string">930439-1323434</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-5254-8762</idno>
              <affiliation ref="#struct-302729"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Gilles</forename>
                <surname>Gauthier</surname>
              </persName>
              <idno type="halauthorid">241000-0</idno>
              <affiliation ref="#struct-56489"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Marielle</forename>
                <surname>Huvé</surname>
              </persName>
              <idno type="halauthorid">151120-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Pascal</forename>
                <surname>Roussel</surname>
              </persName>
              <email type="md5">f9be584b66094972c83de51972ed19c7</email>
              <email type="domain">univ-lille.fr</email>
              <idno type="idhal" notation="string">pascalroussel</idno>
              <idno type="idhal" notation="numeric">9428</idno>
              <idno type="halauthorid" notation="string">2469-9428</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/A-8578-2011</idno>
              <idno type="IDREF">https://www.idref.fr/131004263</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-7243-7293</idno>
              <idno type="GOOGLE SCHOLAR">https://scholar.google.com/citations?user=53C-bPoAAAAJ&amp;hl=fr</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/A-8578-2011</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Valérie</forename>
                <surname>Dupray</surname>
              </persName>
              <email type="md5">7d2f548ecff938d491ce70e53c66bfa8</email>
              <email type="domain">univ-rouen.fr</email>
              <idno type="idhal" notation="string">dupray</idno>
              <idno type="idhal" notation="numeric">170736</idno>
              <idno type="halauthorid" notation="string">1190782-170736</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-6188-0943</idno>
              <idno type="IDREF">https://www.idref.fr/199122326</idno>
              <affiliation ref="#struct-12178"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Lina</forename>
                <surname>Yuan</surname>
              </persName>
              <idno type="idhal" notation="numeric">1323435</idno>
              <idno type="halauthorid" notation="string">852791-1323435</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-3687-2495</idno>
              <affiliation ref="#struct-12178"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Anastasiya</forename>
                <surname>Zadoya</surname>
              </persName>
              <idno type="halauthorid">1821570-0</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Marie</forename>
                <surname>Colmont</surname>
              </persName>
              <email type="md5">692f963b9dff7f1d36e935b7461b64d8</email>
              <email type="domain">centralelille.fr</email>
              <idno type="idhal" notation="string">marie-colmont</idno>
              <idno type="idhal" notation="numeric">19184</idno>
              <idno type="halauthorid" notation="string">3004-19184</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6120-0618</idno>
              <idno type="IDREF">https://www.idref.fr/087390450</idno>
              <affiliation ref="#struct-3209"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Marie</forename>
                <surname>Colmont</surname>
              </persName>
              <email type="md5">d3f191ebc4c07dac11708deb76e8be5b</email>
              <email type="domain">univ-lille.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2023-12-13 08:58:39</date>
              <date type="whenModified">2026-02-07 04:05:46</date>
              <date type="whenReleased">2023-12-13 13:55:12</date>
              <date type="whenProduced">2020-04-14</date>
              <date type="whenEndEmbargoed">2023-12-13</date>
              <ref type="file" target="https://hal.science/hal-04339456v1/document">
                <date notBefore="2023-12-13"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-04339456v1/file/LVO-papier-final-rev_bis_final.pdf" id="file-4339456-3779188">
                <date notBefore="2023-12-13"/>
              </ref>
              <ref type="externalLink" target="https://biblio.ugent.be/publication/8698395/file/8699075"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="113127">
                <persName>
                  <forename>Marie</forename>
                  <surname>Colmont</surname>
                </persName>
                <email type="md5">d3f191ebc4c07dac11708deb76e8be5b</email>
                <email type="domain">univ-lille.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04339456</idno>
            <idno type="halUri">https://hal.science/hal-04339456</idno>
            <idno type="halBibtex">gomeztorres:hal-04339456</idno>
            <idno type="halRefHtml">&lt;i&gt;Inorganic Chemistry&lt;/i&gt;, 2020, 59 (9), pp.5929-5938. &lt;a target="_blank" href="https://dx.doi.org/10.1021/acs.inorgchem.9b03689"&gt;&amp;#x27E8;10.1021/acs.inorgchem.9b03689&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Inorganic Chemistry, 2020, 59 (9), pp.5929-5938. &amp;#x27E8;10.1021/acs.inorgchem.9b03689&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-4339456-3779188"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UNIV-ARTOIS">Université d'Artois</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UCCS">Unité de Catalyse et de Chimie du Solide</idno>
            <idno type="stamp" n="COMUE-NORMANDIE">Normandie Université</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="UNIROUEN">Université de Rouen Normandie</idno>
            <idno type="stamp" n="UNIV-LILLE">Université de Lille</idno>
            <idno type="stamp" n="LABO-SMS">Laboratoire Sciences et Méthodes Séparatives</idno>
            <idno type="stamp" n="TEST-HALCNRS">Collection test HAL CNRS</idno>
            <idno type="stamp" n="LABOS-XL-CHEM">École Universitaire de Recherche (EUR) XL-Chem</idno>
            <idno type="stamp" n="UCCS-CIMEND">UCCS-CIMEND</idno>
            <idno type="stamp" n="UCCS-MISSP">UCCS-MISSP</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Pure and RE 3+ -Doped La7O6 (VO4) 3 (RE = Eu, Sm): Polymorphism Stability and Luminescence Properties of a New Oxyvanadate Matrix</title>
                <author role="aut">
                  <persName>
                    <forename type="first">María Alejandra</forename>
                    <surname>Gómez Torres</surname>
                  </persName>
                  <idno type="halauthorid">1830856-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Anna</forename>
                    <surname>Kaczmarek</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">1323434</idno>
                  <idno type="halauthorid" notation="string">930439-1323434</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-5254-8762</idno>
                  <affiliation ref="#struct-302729"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Gilles</forename>
                    <surname>Gauthier</surname>
                  </persName>
                  <idno type="halauthorid">241000-0</idno>
                  <affiliation ref="#struct-56489"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Marielle</forename>
                    <surname>Huvé</surname>
                  </persName>
                  <idno type="halauthorid">151120-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Pascal</forename>
                    <surname>Roussel</surname>
                  </persName>
                  <email type="md5">f9be584b66094972c83de51972ed19c7</email>
                  <email type="domain">univ-lille.fr</email>
                  <idno type="idhal" notation="string">pascalroussel</idno>
                  <idno type="idhal" notation="numeric">9428</idno>
                  <idno type="halauthorid" notation="string">2469-9428</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/A-8578-2011</idno>
                  <idno type="IDREF">https://www.idref.fr/131004263</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-7243-7293</idno>
                  <idno type="GOOGLE SCHOLAR">https://scholar.google.com/citations?user=53C-bPoAAAAJ&amp;hl=fr</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/A-8578-2011</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Valérie</forename>
                    <surname>Dupray</surname>
                  </persName>
                  <email type="md5">7d2f548ecff938d491ce70e53c66bfa8</email>
                  <email type="domain">univ-rouen.fr</email>
                  <idno type="idhal" notation="string">dupray</idno>
                  <idno type="idhal" notation="numeric">170736</idno>
                  <idno type="halauthorid" notation="string">1190782-170736</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-6188-0943</idno>
                  <idno type="IDREF">https://www.idref.fr/199122326</idno>
                  <affiliation ref="#struct-12178"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Lina</forename>
                    <surname>Yuan</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">1323435</idno>
                  <idno type="halauthorid" notation="string">852791-1323435</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-3687-2495</idno>
                  <affiliation ref="#struct-12178"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Anastasiya</forename>
                    <surname>Zadoya</surname>
                  </persName>
                  <idno type="halauthorid">1821570-0</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Marie</forename>
                    <surname>Colmont</surname>
                  </persName>
                  <email type="md5">692f963b9dff7f1d36e935b7461b64d8</email>
                  <email type="domain">centralelille.fr</email>
                  <idno type="idhal" notation="string">marie-colmont</idno>
                  <idno type="idhal" notation="numeric">19184</idno>
                  <idno type="halauthorid" notation="string">3004-19184</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6120-0618</idno>
                  <idno type="IDREF">https://www.idref.fr/087390450</idno>
                  <affiliation ref="#struct-3209"/>
                </author>
              </analytic>
              <monogr>
                <idno type="localRef">1</idno>
                <idno type="halJournalId" status="VALID">5523</idno>
                <idno type="issn">0020-1669</idno>
                <idno type="eissn">1520-510X</idno>
                <title level="j">Inorganic Chemistry</title>
                <imprint>
                  <publisher>American Chemical Society</publisher>
                  <biblScope unit="volume">59</biblScope>
                  <biblScope unit="issue">9</biblScope>
                  <biblScope unit="pp">5929-5938</biblScope>
                  <date type="datePub">2020-04-14</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/acs.inorgchem.9b03689</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="chim">Chemical Sciences</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Two polytypes of the new oxyvanadate matrix La 7 O 6 (VO 4) 3 were identified and deeply characterized. The crystal structure of the α-polytype was solved using a combination of precession electron diffraction and X-ray powder diffraction techniques. It crystallizes in a monoclinic unit cell with space group P2 1 , a= 13.0148(3) Å, b= 19.1566(5) Å, c= 7.0764(17) Å and β= 99.87(1)°. Its structure is built upon [La 7 O 6 ] +9 polycationic units at the origin of a porous 3D networks evidencing rectangular channels filled by isolated (VO 4) tetrahedra. An in situ High Temperature XRD study highlights a number of complex phase transitions assorted with the existence of a β-polytype also refined in a monoclinic unit cell, space group P2 1 /n, a= 13.0713(4) Å, b= 18.1835(6) Å, c= 7.1382(2) Å and β= 97.31(1)°. Thus, during the transitions, while the polycationic network is almost identical, the vanadate's geometry is largely modified. The use of Eu 3+ and Sm 3+ at different concentrations into the host lattice is possible using solid-state techniques. The photoluminescence (PL), PL excitation (PLE) spectra and luminescence decay times were recorded and discussed. The phosphors present an emission light being bright and reddish-orange after excitation under UV. This is mainly due to the V-O band and f-f transitions. Whatever the studied polytype, the final luminescence properties are retained during the heating/cooling process.</p>
            </abstract>
            <particDesc>
              <org type="consortium">Collaboration</org>
            </particDesc>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-3209" status="VALID">
          <idno type="IdRef">161608809</idno>
          <idno type="ISNI">0000 0004 0368 3038</idno>
          <idno type="RNSR">200612828X</idno>
          <idno type="ROR">https://ror.org/04vrqzz54</idno>
          <idno type="Wikidata">Q3214445</idno>
          <orgName>Unité de Catalyse et Chimie du Solide - UMR 8181</orgName>
          <orgName type="acronym">UCCS</orgName>
          <date type="start">2006-01-01</date>
          <desc>
            <address>
              <addrLine>Cité Scientifique - Bâtiment C3 - 59655 Villeneuve d'Ascq Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://uccs.univ-lille.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR8181" active="#struct-56711" type="direct"/>
            <relation name="UMR8181" active="#struct-120930" type="direct"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR8181" active="#struct-374570" type="direct"/>
            <relation name="UMR8181" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-302729" status="VALID">
          <idno type="ROR">https://ror.org/00cv9y106</idno>
          <orgName>Universiteit Gent = Ghent University = Université de Gand</orgName>
          <orgName type="acronym">UGent</orgName>
          <date type="start">1817-01-01</date>
          <desc>
            <address>
              <addrLine>St. Pietersnieuwstraat 33, 9000 Gent</addrLine>
              <country key="BE"/>
            </address>
            <ref type="url">https://www.ugent.be/en</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-56489" status="VALID">
          <idno type="ROR">https://ror.org/00xc1d948</idno>
          <orgName>Universidad Industrial de Santander [Bucaramanga]</orgName>
          <orgName type="acronym">UIS</orgName>
          <desc>
            <address>
              <addrLine>Cra 27 Calle 9 Ciudad Universitaria Bucaramanga-Santander-Colombia</addrLine>
              <country key="CO"/>
            </address>
            <ref type="url">https://www.uis.edu.co/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-12178" status="OLD">
          <idno type="IdRef">158723953</idno>
          <idno type="RNSR">200014531Z</idno>
          <orgName>Sciences et Méthodes Séparatives</orgName>
          <orgName type="acronym">SMS</orgName>
          <date type="start">2003-01-01</date>
          <date type="end">2021-12-31</date>
          <desc>
            <address>
              <addrLine>Place Emile Blondel, 76821 Mont-Saint-Aignan Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://labsms.univ-rouen.fr/</ref>
          </desc>
          <listRelation>
            <relation name="EA3233" active="#struct-300318" type="direct"/>
            <relation active="#struct-455934" type="indirect"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-56711" status="VALID">
          <idno type="IdRef">034634894</idno>
          <idno type="ISNI">000000012364777X</idno>
          <idno type="ROR">https://ror.org/053x9s498</idno>
          <orgName>Université d'Artois</orgName>
          <orgName type="acronym">UA</orgName>
          <date type="start">1992-09-01</date>
          <desc>
            <address>
              <addrLine>9 rue du Temple - BP 10665 - 62030 Arras cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-artois.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-120930" status="VALID">
          <idno type="IdRef">256304629</idno>
          <idno type="ISNI">0000000122034461</idno>
          <idno type="ROR">https://ror.org/01x441g73</idno>
          <orgName>Centrale Lille</orgName>
          <desc>
            <address>
              <addrLine>École Centrale de Lille - Cité Scientifique - CS 20048 59651 Villeneuve d'Ascq Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://centralelille.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-374570" status="VALID">
          <idno type="IdRef">223446556</idno>
          <idno type="ISNI">0000 0001 2242 6780</idno>
          <idno type="ROR">https://ror.org/02kzqn938</idno>
          <idno type="Wikidata">Q3551621</idno>
          <orgName>Université de Lille</orgName>
          <desc>
            <address>
              <addrLine>EPE Université de Lille. -- 42 rue Paul Duez, 59000 Lille</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-lille.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300318" status="VALID">
          <idno type="IdRef">026403919</idno>
          <idno type="ISNI">0000000121083034</idno>
          <idno type="ROR">https://ror.org/03nhjew95</idno>
          <orgName>Université de Rouen Normandie</orgName>
          <orgName type="acronym">UNIROUEN</orgName>
          <date type="start">1966-01-01</date>
          <desc>
            <address>
              <addrLine>1, rue Thomas Becket 76821 Mont-Saint-Aignan Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-rouen.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-455934" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-455934" status="VALID">
          <idno type="IdRef">190906332</idno>
          <idno type="ISNI">0000000417859671 </idno>
          <idno type="ROR">https://ror.org/01k40cz91</idno>
          <orgName>Normandie Université</orgName>
          <orgName type="acronym">NU</orgName>
          <date type="start">2015-01-01</date>
          <desc>
            <address>
              <addrLine>Esplanade de la Paix - CS 14032 - 14032 Caen Cedex 5</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.normandie-univ.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>