Carborane-based heteromolecular extended networks driven by directional C-Te⋯N chalcogen bonding interactions - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2023

Carborane-based heteromolecular extended networks driven by directional C-Te⋯N chalcogen bonding interactions

Résumé

We demonstrate that o-closo-(TeMe)2carborane directs, in the presence of linear ditopic neutral Lewis bases, the formation of co-crystals with 1D extended supramolecular networks. Specifically, the network formation is systematically stabilized by short and quasi-linear C-TeMIDLINE HORIZONTAL ELLIPSISN chalcogen-bonding (ChB) interactions. In sum, we report efficient carborane-based tectons to rationally design high-dimensional neutral heteromolecular networks. Bis(telluromethyl)-o-carborane directs, in the presence of linear ditopic neutral Lewis bases, the formation of 1D extended supramolecular networks driven by efficient C-TeMIDLINE HORIZONTAL ELLIPSISN chalcogen bonding interactions.

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Chimie
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Dates et versions

hal-04336091 , version 1 (11-12-2023)

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Paternité - Pas d'utilisation commerciale

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Citer

Maxime Beau, Olivier Jeannin, Marc Fourmigué, Emmanuel Aubert, Enrique Espinosa, et al.. Carborane-based heteromolecular extended networks driven by directional C-Te⋯N chalcogen bonding interactions. Chemical Communications, 2023, Chemical Communications, 59 (92), pp.13727-13730. ⟨10.1039/d3cc04338j⟩. ⟨hal-04336091⟩
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