Solubilization of Eucalyptus citriodora essential oil and citronellal in deep eutectic solvents:water:cyclodextrins mixtures - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Molecular Liquids Année : 2022

Solubilization of Eucalyptus citriodora essential oil and citronellal in deep eutectic solvents:water:cyclodextrins mixtures

Résumé

Essential oils (EOs) offer interesting biological properties that can be altered by their high volatility and low solubility. This study examined, for the first time, the effect of the combination of different choline chloride (ChCl) based-deep eutectic solvents (DESs), water and cyclodextrins (CDs) on the retention and solubilization of Eucalyptus citriodora EO and its major component, citronellal. The density, viscosity and polarity of the newly prepared DES:water:CD mixtures were measured. The influence of water content, DES type and composition as well as CD type and concentration on the retention capacity were investigated using static headspace-gas chromatography. Results showed that the mixture composed of choline chloride:urea (ChCl:U) (1:2 molar ratio) DES:water (70:30 wt%) in the presence of CD presented the highest retention capacity. Finally, the formation constant (Kf) values of CD/citronellal inclusion complexes and the vapor-liquid partition coefficients of citronellal were determined in ChCl:U DES:water 70:30 wt%.

Domaines

Chimie

Dates et versions

hal-04320446 , version 1 (04-12-2023)

Identifiants

Citer

Lamia Nakhle, Miriana Kfoury, Isabelle Mallard, Hélène Greige-Gerges, David Landy. Solubilization of Eucalyptus citriodora essential oil and citronellal in deep eutectic solvents:water:cyclodextrins mixtures. Journal of Molecular Liquids, 2022, 359, pp.119371. ⟨10.1016/j.molliq.2022.119371⟩. ⟨hal-04320446⟩
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