Chirality determination in single crystals using XNCD and MChD
Résumé
Octahedral tris(bidentate) coordination complexes are chiral due to the propeller-like arrangement of the ligands around the metal core. The enantiomers of [M(en)3](NO3)2 (M = Mn(II), Co(II), Ni(II), Zn(II); en = ethylenediamine) spontaneously resolve to form a mixture of conglomerate crystals in the space group P6322 at room temperature [1]...
Domaines
Chimie| Origine | Accord explicite pour ce dépôt |
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