Emerging co-synthesis of dimethyl oxalate and dimethyl carbonate using Pd/silicalite-1 catalyst with synergistic interactions of Pd and silanols
Résumé
An emerging synthetic route for the co-synthesis of dimethyl oxalate (DMO) and dimethyl carbonate (DMC) via the indirect oxidative carbonylation of CH 3 OH is presented. The promising co-synthesis process combines the advantages of two separate routes of DMO and DMC syntheses. Herein, palladium containing silicalite-1 zeolite (Pd/S-1) catalyst was first found to be highly active and stable for the
Domaines
ChimieOrigine | Fichiers produits par l'(les) auteur(s) |
---|