<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04280743</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-23T21:35:19+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Weakly Interacting Molecular Spins in On‐Surface Synthesized Nanoclusters on a Graphene Oxide Nanosheet</title>
            <author role="aut">
              <persName>
                <forename type="first">Makoto</forename>
                <surname>Sakurai</surname>
              </persName>
              <idno type="idhal" notation="numeric">1306786</idno>
              <idno type="halauthorid" notation="string">2080777-1306786</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-0909-4608</idno>
              <affiliation ref="#struct-337705"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Tsuyoshi</forename>
                <surname>Ueta</surname>
              </persName>
              <idno type="halauthorid">2950086-0</idno>
              <affiliation ref="#struct-416726"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Christian</forename>
                <surname>Joachim</surname>
              </persName>
              <email type="md5">59f460b9121e7c35459076a0885e1a73</email>
              <email type="domain">cemes.fr</email>
              <idno type="idhal" notation="string">christian-joachim</idno>
              <idno type="idhal" notation="numeric">19546</idno>
              <idno type="halauthorid" notation="string">22762-19546</idno>
              <idno type="IDREF">https://www.idref.fr/070141436</idno>
              <affiliation ref="#struct-233966"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Christian</forename>
                <surname>Joachim</surname>
              </persName>
              <email type="md5">59f460b9121e7c35459076a0885e1a73</email>
              <email type="domain">cemes.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2023-11-11 17:05:26</date>
              <date type="whenModified">2025-11-17 09:54:14</date>
              <date type="whenReleased">2023-11-13 14:51:27</date>
              <date type="whenProduced">2023-10</date>
              <date type="whenEndEmbargoed">2023-11-11</date>
              <ref type="file" target="https://hal.science/hal-04280743v1/document">
                <date notBefore="2023-11-11"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-04280743v1/file/CJ%20Makoto%20Adv.%20Elect.%20Materials%202023.pdf" id="file-4280743-3735088">
                <date notBefore="2023-11-11"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="458976">
                <persName>
                  <forename>Christian</forename>
                  <surname>Joachim</surname>
                </persName>
                <email type="md5">59f460b9121e7c35459076a0885e1a73</email>
                <email type="domain">cemes.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04280743</idno>
            <idno type="halUri">https://hal.science/hal-04280743</idno>
            <idno type="halBibtex">sakurai:hal-04280743</idno>
            <idno type="halRefHtml">&lt;i&gt;Advanced Electronic Materials&lt;/i&gt;, 2023, 9 (10), &lt;a target="_blank" href="https://dx.doi.org/10.1002/aelm.202300347"&gt;&amp;#x27E8;10.1002/aelm.202300347&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Advanced Electronic Materials, 2023, 9 (10), &amp;#x27E8;10.1002/aelm.202300347&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-4280743-3735088"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="IRD">IRD - Institut de recherche pour le développement</idno>
            <idno type="stamp" n="UNIV-TLSE3">Université de Toulouse</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="INSA-TOULOUSE">Institut National des Sciences Appliquées de Toulouse</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="CEMES">Centre d'élaboration de matériaux et d'études structurales</idno>
            <idno type="stamp" n="GNS" corresp="CEMES">Groupe Nanosciences</idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="FERMI" corresp="CNRS">Fédération de recherche « Matière et interactions »</idno>
            <idno type="stamp" n="TOULOUSE-INP">Toulouse - INP</idno>
            <idno type="stamp" n="UNIV-UT3">Université Toulouse 3</idno>
            <idno type="stamp" n="UT3-INP">Université de Toulouse / Toulouse INP</idno>
            <idno type="stamp" n="UT3-TOULOUSEINP">Université de Toulouse / Toulouse INP</idno>
            <idno type="stamp" n="ICT-CHIMIE">ICT-CHIMIE </idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Weakly Interacting Molecular Spins in On‐Surface Synthesized Nanoclusters on a Graphene Oxide Nanosheet</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Makoto</forename>
                    <surname>Sakurai</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">1306786</idno>
                  <idno type="halauthorid" notation="string">2080777-1306786</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-0909-4608</idno>
                  <affiliation ref="#struct-337705"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Tsuyoshi</forename>
                    <surname>Ueta</surname>
                  </persName>
                  <idno type="halauthorid">2950086-0</idno>
                  <affiliation ref="#struct-416726"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Christian</forename>
                    <surname>Joachim</surname>
                  </persName>
                  <email type="md5">59f460b9121e7c35459076a0885e1a73</email>
                  <email type="domain">cemes.fr</email>
                  <idno type="idhal" notation="string">christian-joachim</idno>
                  <idno type="idhal" notation="numeric">19546</idno>
                  <idno type="halauthorid" notation="string">22762-19546</idno>
                  <idno type="IDREF">https://www.idref.fr/070141436</idno>
                  <affiliation ref="#struct-233966"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">108620</idno>
                <idno type="issn">2199-160X</idno>
                <idno type="eissn">2199-160X</idno>
                <title level="j">Advanced Electronic Materials</title>
                <imprint>
                  <publisher>Wiley</publisher>
                  <biblScope unit="volume">9</biblScope>
                  <biblScope unit="issue">10</biblScope>
                  <date type="datePub">2023-10</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1002/aelm.202300347</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <classCode scheme="halDomain" n="phys">Physics [physics]</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Abstract With an average diameter of ≈2 nm, on‐surface synthesized amino‐ferrocene nanoclusters are chemisorbed onto a graphene oxide nanosheet, where their Fe ions are in an S = 5/2 high‐spin state. In this two‐dimensional (2D) nanomaterial, the molecular spins in a given nanocluster are weakly magnetic dipole interacting. It generates spin correlations and slow dynamics accessible by magnetic susceptibility and Mössbauer spectroscopy at a temperature where the magnetic anisotropy is negligible. Magnetic simulations show that minimizing their magnetic dipole energies produces spatially entangled structures of the spin orientations under thermal fluctuations at T ≲ 15 K and that the structures behave like a spin liquid. The competition between the formation of the structures and their thermal destruction generates slow dynamics. The ability to create emergent functionalities from dense stacks of weakly interacting magnetic molecules in a 2 nm space paves the way for new designs of an ultra‐compact building block and a functional component in 2D spintronic and neuromorphic devices.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-337705" status="VALID">
          <orgName>International Center for Materials Nanoarchitectonics</orgName>
          <orgName type="acronym">WPI-MANA</orgName>
          <desc>
            <address>
              <addrLine>1-1 Namiki Tsukuba, Ibaraki 305-0044 JAPAN</addrLine>
              <country key="JP"/>
            </address>
            <ref type="url">https://www.nims.go.jp/mana/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-416726" status="VALID">
          <idno type="ROR">https://ror.org/039ygjf22</idno>
          <orgName>The Jikei University School of Medicine</orgName>
          <desc>
            <address>
              <addrLine>3-25-8, Nishi-Shimbashi, Minato-ku,Tokyo, 105-8461</addrLine>
              <country key="JP"/>
            </address>
            <ref type="url">http://www.jikei.ac.jp/eng/</ref>
          </desc>
        </org>
        <org type="researchteam" xml:id="struct-233966" status="OLD">
          <orgName>Groupe NanoSciences</orgName>
          <orgName type="acronym">CEMES-GNS</orgName>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>CEMES 29 rue Jeanne Marvig, BP 94347, F-31055 Toulouse Cedex 4</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cemes.fr/GNS</ref>
          </desc>
          <listRelation>
            <relation active="#struct-460" type="direct"/>
            <relation active="#struct-116255" type="indirect"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-443875" type="indirect"/>
            <relation active="#struct-159253" type="indirect"/>
            <relation active="#struct-67872" type="indirect"/>
            <relation active="#struct-217752" type="indirect"/>
            <relation active="#struct-341038" type="indirect"/>
            <relation name="UAR2599 / FR2599" active="#struct-441569" type="indirect"/>
            <relation active="#struct-448187" type="indirect"/>
            <relation name="UPR8011" active="#struct-441569" type="indirect"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-460" status="OLD">
          <idno type="IdRef">157408132</idno>
          <idno type="ISNI">0000 0000 9254 7345</idno>
          <idno type="RNSR">199117683P</idno>
          <idno type="ROR">https://ror.org/03kwnqq69</idno>
          <orgName>Centre d'élaboration de matériaux et d'études structurales</orgName>
          <orgName type="acronym">CEMES</orgName>
          <date type="start">1988-01-01</date>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>29 Rue Jeanne Marvig - BP 94347 31055 TOULOUSE CEDEX 4</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cemes.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-116255" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-443875" type="indirect"/>
            <relation active="#struct-159253" type="direct"/>
            <relation active="#struct-67872" type="indirect"/>
            <relation active="#struct-217752" type="direct"/>
            <relation active="#struct-341038" type="indirect"/>
            <relation name="UAR2599 / FR2599" active="#struct-441569" type="direct"/>
            <relation active="#struct-448187" type="indirect"/>
            <relation name="UPR8011" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-116255" status="VALID">
          <idno type="IdRef">026388766</idno>
          <idno type="ISNI">0000 0001 2286 8343</idno>
          <idno type="ROR">https://ror.org/01h8pf755</idno>
          <idno type="Wikidata">Q858979</idno>
          <orgName>Institut National des Sciences Appliquées - Toulouse</orgName>
          <orgName type="acronym">INSA Toulouse</orgName>
          <date type="start">1963-10-21</date>
          <desc>
            <address>
              <addrLine>135, avenue de Rangueil - 31077 Toulouse cedex 4</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-toulouse.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301232" type="direct"/>
            <relation active="#struct-443875" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-443875" status="VALID">
          <idno type="ROR">https://ror.org/017tgbk05</idno>
          <orgName>Communauté d'universités et établissements de Toulouse</orgName>
          <orgName type="acronym">Comue de Toulouse</orgName>
          <desc>
            <address>
              <addrLine>41 Allée Jules Guesde, 31000 Toulouse</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-toulouse.fr/</ref>
          </desc>
        </org>
        <org type="regrouplaboratory" xml:id="struct-159253" status="OLD">
          <idno type="IdRef">240309472</idno>
          <idno type="ISNI">0000 0004 4686 8315</idno>
          <idno type="RNSR">200310667L</idno>
          <orgName>Institut de Chimie de Toulouse</orgName>
          <orgName type="acronym">ICT</orgName>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>118 Route de Narbonne 31062 Toulouse cédex 9</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-67872" type="direct"/>
            <relation active="#struct-217752" type="direct"/>
            <relation active="#struct-443875" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UAR2599 / FR2599" active="#struct-441569" type="direct"/>
            <relation active="#struct-448187" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-67872" status="VALID">
          <idno type="IdRef">050165224</idno>
          <idno type="ROR">https://ror.org/05q3vnk25</idno>
          <orgName>Institut de Recherche pour le Développement</orgName>
          <orgName type="acronym">IRD</orgName>
          <desc>
            <address>
              <addrLine>SiègeLe Sextant 44, bd de DunkerqueCS 9000913572 Marseille cedex 02</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.ird.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-217752" status="OLD">
          <idno type="IdRef">026404672</idno>
          <idno type="ISNI">0000000121617331</idno>
          <idno type="ROR">https://ror.org/02v6kpv12</idno>
          <idno type="Wikidata">Q1273188</idno>
          <orgName>Université Toulouse III - Paul Sabatier</orgName>
          <orgName type="acronym">UT3</orgName>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>118 route de Narbonne - 31062 Toulouse</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-tlse3.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-443875" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-448187" status="VALID">
          <idno type="IdRef">026388820</idno>
          <idno type="ISNI">0000000121766169</idno>
          <idno type="ROR">https://ror.org/033p9g875</idno>
          <orgName>Institut National Polytechnique (Toulouse)</orgName>
          <orgName type="acronym">Toulouse INP</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.inp-toulouse.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-443875" type="direct"/>
          </listRelation>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>