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Article Dans Une Revue Journal of Colloid and Interface Science Année : 2024

Nitrogen sites prevail over textural properties in N-doped carbons for the oxygen reduction reaction

Javier Quílez-Bermejo
Sara Pérez-Rodríguez
Daniel Torres
Rafael Canevesi
Diego Cazorla-Amorós
Vanessa Fierro

Résumé

Nitrogen-doped carbon-based electrodes are among the most promising alternatives to platinum-based electrodes in the cathode of fuel cells and metal-air batteries, where the oxygen reduction reaction (ORR) takes place. Among the approaches for improving ORR activity, nitrogen functionalities and well-developed textural properties have proved very effective. Nonetheless, the question of which between nitrogen active sites or textural properties are more crucial in N-doped carbon materials remains unanswered. This work proposes a comparative and critical approach through the selective functionalization of four commercial activated carbons with different textural properties. This study highlights the greater importance of N-doping in relation to the textural properties of carbon materials, and provides fundamental insights for conclusively addressing the ongoing debate within the carbon community about the significance of these two factors in the context of ORR.

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Dates et versions

hal-04274120 , version 1 (07-11-2023)

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Paternité - Pas d'utilisation commerciale - Pas de modification

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Javier Quílez-Bermejo, Sara Pérez-Rodríguez, Daniel Torres, Rafael Canevesi, Emilia Morallón, et al.. Nitrogen sites prevail over textural properties in N-doped carbons for the oxygen reduction reaction. Journal of Colloid and Interface Science, 2024, 654, pp.446-453. ⟨10.1016/j.jcis.2023.10.013⟩. ⟨hal-04274120⟩
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