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Journal Articles The Journal of Chemical Physics Year : 2013

Communication: Evidence of structural phase transitions in silicalite-1 by infrared spectroscopy

Abstract

The adsorption of trichloroethylene, perchloroethylene, and p-xylene on a MFI (Mobile-FIve) zeolite is studied using in situ FTIR spectroscopy at 298 K. Spectra of self-supported zeolites in contact with increasing pressures of pure gas were recorded at equilibrium in the mid-infrared domain. Analysis of the evolution of the shape and location of vibrational bands of the zeolite as a function of the amount adsorbed allowed the observation of structural modifications of the adsorbent for the first time by infrared spectroscopy.
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hal-04237958 , version 1 (11-10-2023)

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Anthony Ballandras, Guy Weber, Christian Paulin, Jean-Pierre Bellat, Maud Rotger. Communication: Evidence of structural phase transitions in silicalite-1 by infrared spectroscopy. The Journal of Chemical Physics, 2013, 139 (9), ⟨10.1063/1.4819080⟩. ⟨hal-04237958⟩
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