Article Dans Une Revue ACS Macro Letters Année : 2015

One-Pot Three-Step Polymerization System Using Double Click Michael Addition and Radical Photopolymerization

Résumé

A click chemistry synthetic strategy based on aza-Michael addition and radical photopolymerization is proposed to generate a polymeric network via three time-controlled steps. The selection of primary diamines and diacrylates allows two consecutive aza-Michael reactions to occur. This reaction sequence affords the unique opportunity to interpose a radical photopolymerization reaction, enhancing the cross-link density. Consequently, the second aza-Michael addition appears as a valuable postconsolidation step of the polymer network.

Domaines

Fichier non déposé

Dates et versions

hal-04234067 , version 1 (09-10-2023)

Identifiants

Citer

Matthieu Retailleau, Ahmad Ibrahim, Celine Croutxe-Barghorn, Xavier Allonas, Christian Ley, et al.. One-Pot Three-Step Polymerization System Using Double Click Michael Addition and Radical Photopolymerization. ACS Macro Letters, 2015, 4 (12), pp.1327-1331. ⟨10.1021/acsmacrolett.5b00675⟩. ⟨hal-04234067⟩
57 Consultations
0 Téléchargements

Altmetric

Partager

  • More