Role of organic solvent and influence of oxidant in the oxidation of linalool catalyzed by molybdenum and vanadium complexes - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Tetrahedron Green Chem Année : 2023

Role of organic solvent and influence of oxidant in the oxidation of linalool catalyzed by molybdenum and vanadium complexes

Résumé

The coordination complexes [MoO2(SAP)]2 [Mo] and [VO(SAP)]2O [V] (SAP = salicylideneamino-phenolato) were tested as pre-catalysts for oxidation of a biomass-issued substrate, linalool (L). The reaction was studied using different oxidants, TBHP (in water or in decane) or H2O2 (in water with/without acetonitrile). Efficient linalool (L) conversions were obtained with selectivity towards two selected products, 2-(5-methyl-5- vinyltetrahydro-furan-2-yl propan-2-ol) (1) and 2,2,6- trimethyl-6-vinyltetrahydro-2H-pyran-3-ol (2) depending on pre-catalysts and oxidant. Green metrics have been calculated and showed the role of organic solvent for the process.
Fichier principal
Vignette du fichier
Haidar, Role of organic solvent and influence of oxidant in the oxidation, 2023.pdf (696.27 Ko) Télécharger le fichier
Origine : Fichiers éditeurs autorisés sur une archive ouverte
Licence : CC BY NC ND - Paternité - Pas d'utilisation commerciale - Pas de modification

Dates et versions

hal-04233003 , version 1 (09-10-2023)

Licence

Paternité - Pas d'utilisation commerciale - Pas de modification

Identifiants

Citer

Ali Al Hadi Haidar, Dominique Agustin. Role of organic solvent and influence of oxidant in the oxidation of linalool catalyzed by molybdenum and vanadium complexes. Tetrahedron Green Chem, 2023, 2, pp.100029. ⟨10.1016/j.tgchem.2023.100029⟩. ⟨hal-04233003⟩
5 Consultations
25 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More