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Article Dans Une Revue Materials Today Communications Année : 2023

Influence of the oxidation on the optical properties of Mo-Si-Ti, Ta-Mo-Cr-Al and Ta-Mo-Cr-Ti-Al alloys

Résumé

Three refractory element-based alloys were oxidized for 6 h at 1100 °C in air inside a muffle furnace and the way the oxidation, especially through the evolution of the surface composition and roughness, affects the optical properties of these materials is discussed here. The ternary Mo-20.0Si-52.8Ti (at.%) serves as an example of Mo-based alloys, while the equimolar Ta-Mo-Cr-Al (TMCA) and Ta-Mo-Cr-Ti-Al (TMCTA) are typical of the class of oxidation-resistant refractory compositionally complex alloys. The normal spectral emissivity of these three samples was increased due to the oxidation process. Oxidized TMCA and TMCTA exhibit a solar absorptivity higher than that of state-of-the-art Ni-based alloys used for solar receivers in concentrated solar power plants. Thus, the two refractory compositionally complex alloys are considered promising candidates for solar thermal energy conversion application.
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Dates et versions

hal-04228351 , version 1 (04-10-2023)

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Ludovic Charpentier, Alexander Kauffmann, Eric Bêche, Christophe Escape, Stephan Laube, et al.. Influence of the oxidation on the optical properties of Mo-Si-Ti, Ta-Mo-Cr-Al and Ta-Mo-Cr-Ti-Al alloys. Materials Today Communications, 2023, 37, pp.107056. ⟨10.1016/j.mtcomm.2023.107056⟩. ⟨hal-04228351⟩
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