Experimental Measurements and Modeling of Vapor–Liquid Equilibria for Eight Mixtures Containing trans -1-Chloro-3,3,3-trifluoropropene (R1233zd(E)) and 2-Chloro-3,3,3-trifluoropropene (R1233xf) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Chemical and Engineering Data Année : 2023

Experimental Measurements and Modeling of Vapor–Liquid Equilibria for Eight Mixtures Containing trans -1-Chloro-3,3,3-trifluoropropene (R1233zd(E)) and 2-Chloro-3,3,3-trifluoropropene (R1233xf)

Résumé

Isothermal vapor-liquid equilibria (VLE) for eight binary systems involving R1233zd(E) (R1233zd(E)+Butane, R1233zd(E)+CO2, R1233zd(E)+HCl, R1233zd(E)+R134a, R1233zd(E)+R152a, R1233zd(E)+R245fa) and R1233xf (R1233xf+R134a, R1233xf+R152a, R1233xf+R245fa) were measured at temperatures from 263 to 353 K. The experiments were conducted by means of a static analytic apparatus with phase analysis via gas chromatography, with resulting maximum expanded uncertainties of 0.2 K for temperatures, 10 kPa for pressure and 0.04 for vapor and liquid mole fractions. The main advantage of the equipment is that vapor and liquid samples are taken from vapor and liquid phase by two capillary samplers (ROLSI®). The Peng-Robinson equation of state and a modified Patel-Teja equation of state are both considered to represent the experimental data. If possible, comparison between the new experimental data and prediction with REFPROP 10.0 software are realized.
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hal-04197103 , version 1 (05-09-2023)

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Jamal El Abbadi, Julien Brocus, Alain Valtz, Christophe Coquelet, Houriez Céline. Experimental Measurements and Modeling of Vapor–Liquid Equilibria for Eight Mixtures Containing trans -1-Chloro-3,3,3-trifluoropropene (R1233zd(E)) and 2-Chloro-3,3,3-trifluoropropene (R1233xf). Journal of Chemical and Engineering Data, 2023, 68 (9), pp.2316-2331. ⟨10.1021/acs.jced.3c00296⟩. ⟨hal-04197103⟩
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