Spin crossover in mixed-anion Fe(NH 2 trz) 3 (BF 4 )(SiF 6 ) 0.5 crystalline rod-shaped particles: the strength of the solid–liquid post synthetic modification - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2023

Spin crossover in mixed-anion Fe(NH 2 trz) 3 (BF 4 )(SiF 6 ) 0.5 crystalline rod-shaped particles: the strength of the solid–liquid post synthetic modification

Résumé

A pure mixed-anion Fe(NH2trz)3(BF4)(SiF6)0.5 spin crossover complex is obtained implementing a solid–liquid post synthetic modification approach from the Fe(NH2trz)3(BF4)2 parent complex. This method allows obtaining highly crystalline powder samples incorporating homogeneous micrometric (1 μm long) rod-shaped particles. This compound presents an abrupt spin crossover behaviour with a narrow (10 K) hysteresis loop centred just above room temperature (320 K) which makes it very interesting for future integration into devices for various applications.
Fichier principal
Vignette du fichier
Yang, Spin crossover in mixed-anion Fe(NH2trz)3(BF4)(SiF6)0.5 crystalline, 2023.pdf (668.23 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-04174161 , version 1 (31-07-2023)

Identifiants

Citer

Xinyu Yang, Alejandro Enriquez-Cabrera, Dorian Toha, Yannick Coppel, Lionel Salmon, et al.. Spin crossover in mixed-anion Fe(NH 2 trz) 3 (BF 4 )(SiF 6 ) 0.5 crystalline rod-shaped particles: the strength of the solid–liquid post synthetic modification. Dalton Transactions, 2023, 52 (30), pp.10828-10834. ⟨10.1039/D3DT02003G⟩. ⟨hal-04174161⟩
36 Consultations
7 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More