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Article Dans Une Revue Dyes and Pigments Année : 2023

Selective ion sensing in aqueous media with ESIPT active fluorescent probes – A particular case for hypochlorite detection

Résumé

We report two ESIPT active novel fluorescent probes, 1 and 2, based on benzoxazole and benzimidazole units, respectively. Their sensing aptitude towards metal ions in aqueous media is reported. A specific response of 1 to Al 3+ and, to a lesser extent, Zn 2+ , was found, while the emission of 2 is highly impacted by the Al 3+ , Cu 2+ , Fe 2+ and Fe 3+ metal ions by either a blue shift or a quenching of the emission. Emission of 2 also shows a relative sensitivity to the Ni 2+ and Hg 2+ cations. Anions sensing studies on 2 revealed a unique emission in presence of hypochlorite ions, while glyphosate and aminomethylphosphonic acid have the effect to decrease the emission intensity by 40% and 75%, respectively. Investigations on the recognition mechanism led to the conclusion that Al 3+ was inhibiting the ESIPT process by deprotonation of the phenol group, and that a fast but weak interaction was taking place between the hypochlorite ion and 2.

Domaines

Chimie
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Dates et versions

hal-04163331 , version 1 (17-07-2023)

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Christian Julio Murga Cotrina, Arghyadeep Bhattacharyya, Shenming Wang, Baptiste Amouroux, Nicolas Casaretto, et al.. Selective ion sensing in aqueous media with ESIPT active fluorescent probes – A particular case for hypochlorite detection. Dyes and Pigments, 2023, 218, ⟨10.1016/j.dyepig.2023.111524⟩. ⟨hal-04163331⟩
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