Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings ("Featured in Org. Chem. Highlights » / https://www.organic-chemistry.org/Highlights/2023/11December.shtm) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2023

Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings ("Featured in Org. Chem. Highlights » / https://www.organic-chemistry.org/Highlights/2023/11December.shtm)

Résumé

An access to functionalised eight-membered carbocyclic ring compounds was developed by simply stirring an unusual vinylogous Donor-Acceptor Cyclopropane (DAC) in boiling o-xylene. Both experimental and computational studies were performed to explain the diastereoselectivity/regioselectivity transfer observed and to provide an overall picture of the mechanism.

Domaines

Chimie organique
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Dates et versions

hal-04153558 , version 1 (11-10-2023)

Identifiants

Citer

Kévin Masson, Maxime Dousset, Bohdan Biletskyi, Sara Chentouf, Jean‐valère Naubron, et al.. Designing Donor‐Acceptor Cyclopropane for the ThermalSynthesis of Carbocyclic Eight‐Membered Rings ("Featured in Org. Chem. Highlights » / https://www.organic-chemistry.org/Highlights/2023/11December.shtm). Advanced Synthesis and Catalysis, 2023, 365 (7), pp.1002-1011. ⟨10.1002/adsc.202300015⟩. ⟨hal-04153558⟩

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