<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-04151296</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-04-25T20:46:09+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Improvement of Barrier Properties of Biodegradable Polybutylene Succinate/Graphene Nanoplatelets Nanocomposites Prepared by Melt Process</title>
            <author role="aut">
              <persName>
                <forename type="first">Raphaël</forename>
                <surname>Cosquer</surname>
              </persName>
              <idno type="idhal" notation="numeric">1166453</idno>
              <idno type="halauthorid" notation="string">2588840-1166453</idno>
              <idno type="IDREF">https://www.idref.fr/264323874</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8665-9428</idno>
              <affiliation ref="#struct-203996"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Sébastien</forename>
                <surname>Pruvost</surname>
              </persName>
              <email type="md5">09507ea528af4f7cce71084b73ee17d1</email>
              <email type="domain">insa-lyon.fr</email>
              <idno type="idhal" notation="string">sebastien-pruvost</idno>
              <idno type="idhal" notation="numeric">735565</idno>
              <idno type="halauthorid" notation="string">19225-735565</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3270-5668</idno>
              <idno type="IDREF">https://www.idref.fr/075878631</idno>
              <affiliation ref="#struct-203996"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Fabrice</forename>
                <surname>Gouanvé</surname>
              </persName>
              <email type="md5">1055e6c7a68618dea293fcc27fc2e268</email>
              <email type="domain">univ-lyon1.fr</email>
              <idno type="idhal" notation="numeric">859298</idno>
              <idno type="halauthorid" notation="string">385411-859298</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-9097-8106</idno>
              <affiliation ref="#struct-203996"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Sebastien</forename>
                <surname>PRUVOST</surname>
              </persName>
              <email type="md5">09507ea528af4f7cce71084b73ee17d1</email>
              <email type="domain">insa-lyon.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2023-07-04 18:30:52</date>
              <date type="whenModified">2026-04-23 14:50:05</date>
              <date type="whenReleased">2023-07-04 18:46:16</date>
              <date type="whenProduced">2021</date>
              <date type="whenEndEmbargoed">2023-07-04</date>
              <ref type="file" target="https://hal.science/hal-04151296v1/document">
                <date notBefore="2023-07-04"/>
              </ref>
              <ref type="file" subtype="greenPublisher" n="1" target="https://hal.science/hal-04151296v1/file/2021_Cosquer_PBS%20GnP_Membranes_2021.pdf" id="file-4151296-3615224">
                <date notBefore="2023-07-04"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="396466">
                <persName>
                  <forename>Sebastien</forename>
                  <surname>PRUVOST</surname>
                </persName>
                <email type="md5">09507ea528af4f7cce71084b73ee17d1</email>
                <email type="domain">insa-lyon.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-04151296</idno>
            <idno type="halUri">https://hal.science/hal-04151296</idno>
            <idno type="halBibtex">cosquer:hal-04151296</idno>
            <idno type="halRefHtml">&lt;i&gt;Membranes&lt;/i&gt;, 2021, 11 (2), pp.151. &lt;a target="_blank" href="https://dx.doi.org/10.3390/membranes11020151"&gt;&amp;#x27E8;10.3390/membranes11020151&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Membranes, 2021, 11 (2), pp.151. &amp;#x27E8;10.3390/membranes11020151&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-4151296-3615224"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="UNIV-ST-ETIENNE">Université Jean Monnet - Saint-Etienne</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-LYON1">Université Claude Bernard - Lyon I</idno>
            <idno type="stamp" n="INSA-LYON">Institut National des Sciences Appliquées de Lyon</idno>
            <idno type="stamp" n="IMP" corresp="UNIV-ST-ETIENNE">Ingénierie des Matériaux Polymères</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="INSA-GROUPE">Groupe INSA</idno>
            <idno type="stamp" n="UDL">UDL</idno>
            <idno type="stamp" n="UNIV-LYON">Université de Lyon</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Improvement of Barrier Properties of Biodegradable Polybutylene Succinate/Graphene Nanoplatelets Nanocomposites Prepared by Melt Process</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Raphaël</forename>
                    <surname>Cosquer</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">1166453</idno>
                  <idno type="halauthorid" notation="string">2588840-1166453</idno>
                  <idno type="IDREF">https://www.idref.fr/264323874</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8665-9428</idno>
                  <affiliation ref="#struct-203996"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Sébastien</forename>
                    <surname>Pruvost</surname>
                  </persName>
                  <email type="md5">09507ea528af4f7cce71084b73ee17d1</email>
                  <email type="domain">insa-lyon.fr</email>
                  <idno type="idhal" notation="string">sebastien-pruvost</idno>
                  <idno type="idhal" notation="numeric">735565</idno>
                  <idno type="halauthorid" notation="string">19225-735565</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3270-5668</idno>
                  <idno type="IDREF">https://www.idref.fr/075878631</idno>
                  <affiliation ref="#struct-203996"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Fabrice</forename>
                    <surname>Gouanvé</surname>
                  </persName>
                  <email type="md5">1055e6c7a68618dea293fcc27fc2e268</email>
                  <email type="domain">univ-lyon1.fr</email>
                  <idno type="idhal" notation="numeric">859298</idno>
                  <idno type="halauthorid" notation="string">385411-859298</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-9097-8106</idno>
                  <affiliation ref="#struct-203996"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">69695</idno>
                <idno type="issn">2077-0375</idno>
                <title level="j">Membranes</title>
                <imprint>
                  <publisher>MDPI</publisher>
                  <biblScope unit="volume">11</biblScope>
                  <biblScope unit="issue">2</biblScope>
                  <biblScope unit="pp">151</biblScope>
                  <date type="datePub">2021</date>
                </imprint>
              </monogr>
              <idno type="doi">10.3390/membranes11020151</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">water sorption</term>
                <term xml:lang="en">water and dioxygen permeability</term>
                <term xml:lang="en">melt blending</term>
                <term xml:lang="en">polybutylene succinate</term>
                <term xml:lang="en">graphene nanocomposites</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.poly">Chemical Sciences/Polymers</classCode>
              <classCode scheme="halDomain" n="chim.geni">Chemical Sciences/Chemical engineering</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Polybutylene Succinate (PBS)/Graphene nanoplatelets (GnP) nanocomposites over a range of GnP from 0 to 1.35 wt.%. were prepared by a melt process. A mixture of individual graphene nanosheets and aggregates was obtained by the addition of GnP in the PBS matrix. The presence of these fillers did not significantly modify the morphology, crystalline microstructure of the matrix or its thermal stability. However, a slight reinforcement effect of PBS was reported in the presence of GnP. The water sorption isotherm modelling with Guggenheim, Andersen and De Boer (GAB) equation and Zimm-Lundberg theory allowed a phenomenological analysis at the molecular scale. The presence of GnP did not modify the water sorption capacity of the PBS matrix. From a kinetic point of view, a decrease of the diffusion coefficient with the increasing GnP content was obtained and was attributed to a tortuosity effect. The influence of water activity was discussed over a range of 0.5 to 1 and 0 to 0.9 for water and dioxygen permeability. Improvement of the barrier properties by 38% and 35% for water and dioxygen permeability respectively were obtained.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-203996" status="VALID">
          <idno type="IdRef">14971677X</idno>
          <idno type="ISNI">0000000403836671</idno>
          <idno type="RNSR">200711890Y</idno>
          <idno type="ROR">https://ror.org/02160my55</idno>
          <orgName>Ingénierie des Matériaux Polymères</orgName>
          <orgName type="acronym">IMP</orgName>
          <date type="start">2007-01-01</date>
          <desc>
            <address>
              <addrLine>17, Av. Jean Capelle 69621 Villeurbanne Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.imp.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-194495" type="direct"/>
            <relation active="#struct-301088" type="indirect"/>
            <relation active="#struct-219748" type="direct"/>
            <relation active="#struct-301232" type="indirect"/>
            <relation active="#struct-300284" type="direct"/>
            <relation active="#struct-1327915" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UMR5223" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-194495" status="VALID">
          <idno type="IdRef">026402823</idno>
          <idno type="ISNI">0000000121686185</idno>
          <idno type="ROR">https://ror.org/029brtt94</idno>
          <orgName>Université Claude Bernard Lyon 1</orgName>
          <orgName type="acronym">UCBL</orgName>
          <desc>
            <address>
              <addrLine>43, boulevard du 11 novembre 1918, 69622 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-lyon1.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301088" status="VALID">
          <idno type="ROR">https://ror.org/01rk35k63</idno>
          <orgName>Université de Lyon</orgName>
          <desc>
            <address>
              <addrLine>92 rue Pasteur - CS 30122, 69361 Lyon Cedex 07</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.universite-lyon.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-219748" status="VALID">
          <idno type="IdRef">052444724</idno>
          <idno type="ISNI">0000 0001 2292 0228</idno>
          <orgName>Institut National des Sciences Appliquées de Lyon</orgName>
          <orgName type="acronym">INSA Lyon</orgName>
          <date type="start">1957-03-18</date>
          <desc>
            <address>
              <addrLine>20 Avenue Albert Einstein, 69621 Villeurbanne cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.insa-lyon.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-301088" type="direct"/>
            <relation active="#struct-301232" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-301232" status="VALID">
          <idno type="IdRef">162105150</idno>
          <orgName>Institut National des Sciences Appliquées</orgName>
          <orgName type="acronym">INSA</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300284" status="VALID">
          <idno type="IdRef">028209966</idno>
          <idno type="ISNI">0000 0001 2158 1682</idno>
          <idno type="ROR">https://ror.org/04yznqr36</idno>
          <idno type="Wikidata">Q623154</idno>
          <orgName>Université Jean Monnet - Saint-Étienne</orgName>
          <orgName type="acronym">UJM</orgName>
          <date type="start">1969-03-27</date>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>10, Rue Tréfilerie – CS 8230142023 Saint-Étienne Cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-st-etienne.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-1327915" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-1327915" status="VALID">
          <idno type="IdRef">285395831</idno>
          <orgName>Université Jean Monnet (EPSCPE)</orgName>
          <orgName type="acronym">UJM EPE</orgName>
          <date type="start">2025-01-01</date>
          <desc>
            <address>
              <addrLine>10 rue Tréfilerie42100 Saint-Etienne</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-st-etienne.fr/fr/index.html</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>