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Article Dans Une Revue Physical Chemistry Chemical Physics Année : 2023

Quantitative analysis of cross-talk in partly deuterated samples of nuclear spins hyperpolarized by dynamic nuclear polarization (DNP) in the thermal mixing regime

Résumé

DNP cross-talk experiments in the thermal mixing regime provide energy transfer rates between the different reservoirs. The dependence of the kinetic parameters on the radical concentration and H/D ratio sheds light onto the nature of “hidden” spins.
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Dates et versions

hal-04114449 , version 1 (01-06-2023)

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Bogdan A Rodin, Vineeth Francis Thalakottoor, Mathieu Baudin, Nicolas Birilirakis, Geoffrey Bodenhausen, et al.. Quantitative analysis of cross-talk in partly deuterated samples of nuclear spins hyperpolarized by dynamic nuclear polarization (DNP) in the thermal mixing regime. Physical Chemistry Chemical Physics, 2023, 25 (21), pp.15040-15051. ⟨10.1039/d3cp00453h⟩. ⟨hal-04114449⟩
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