A lot of geographers, scientists believe that the current climate has changed. Especially, since the rapid increment of world's population. Indeed, rapid urbanization led to an increased demand of basic facilities, such as public transport services, hospitals, housing &, etc. Accordingly; the urban areas of cities have been expanded compared to rural areas, and many modifications and changes have been happened on their surface's materials. These modifications made our cities hotter than the Countryside, UHI effect phenomenon now well-known. One of the main reasons behind these changes is construction materials in both buildings and urban spaces, which play a major role in affecting the urban temperatures, precisely near-surface air temperatures positively or negatively, which depend mainly on the behaviour of the surface with solar radiation and how the energy is reflected, emitted, and absorbed. Thus, the current study aimed to investigate the direct and indirect impacts of materials reflection coefficient on the environmental performance and external urban surface temperature; by using the SOLENE-microclimate model tool (developed by the laboratory CRENAU - ENSA Nantes); which is a direct effect on external air temperature in terms of sustainability in the urban context. This study applied on one of the most important residential complexes in Mosul city - Iraq as a case study. The results were proved that when used a material with high reflectivity; Comparing low albedo Scenario(1) with high albedo Scenario(3); it can improve the thermal behaviour of building and urban surfaces, where the surfaces temperature of rooftop, walls, urban spaces, road have been changed by, respectively, 25°C, 18°C, 20°C, and 18°C. As well as changed the urban air temperature by 11°C. However, the results showed that in some cases the surface temperatures increased slightly even when reflectivity increased in the scene, (comparison scenario 3 and scenario 5) where the change of albedo value of external walls surfaces have affected increasing the average urban spaces & pavement temperature about 2°C. The tool that is used in this study (SOLENE-microclimate) has effectively helped in achieving all the analysis required successfully, which it represent the most specialized tool in this field.