Iridium(I) complexes with bidentate NHC ligands as catalysts for dehydrogenative directed C-H silylation
Résumé
A series of (NHC)(cod)Ir(I) complexes bearing NHC-carboxylate ligands were efficiently synthesized and fully characterized. Their solid-state structures confirmed the bidentate coordination mode of these LX-type NHC ligands. These unprecedented iridium(I) complexes demonstrated efficient catalytic activities in dehydrogenative directed C-H silylation of arenes, and allowed for excellent ortho-selectivity control with aromatic silylating agents.
Domaines
Chimie de coordination
Fichier principal
Manguin, Iridium(I) complexes with bidentate NHC ligands, 2023.pdf (911.79 Ko)
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