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Article Dans Une Revue Phosphorus, Sulfur, and Silicon and the Related Elements Année : 2023

Reactions of substituted arynes and diphenylphosphine oxide or diphenylphosphine-borane complex toward dibenzophospholes – impact of aryne substituents

Résumé

The reaction of diphenylphosphine oxide successively with two aryne precursors was investigated in order to access valuable functionalizable non-symmetrical dibenzophospholes. The reactions proved sensitive to substituents of aryne precursors able to coordinate the incoming lithiated nucleophile.
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hal-04057602 , version 1 (04-04-2023)

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Marie-Charlotte Belhomme, Thomas Guérin, Armen Panossian, Frédéric R Leroux. Reactions of substituted arynes and diphenylphosphine oxide or diphenylphosphine-borane complex toward dibenzophospholes – impact of aryne substituents. Phosphorus, Sulfur, and Silicon and the Related Elements, 2023, 198, ⟨10.1080/10426507.2023.2168270⟩. ⟨hal-04057602⟩
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