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Article Dans Une Revue Chemistry - A European Journal Année : 2023

Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities

Résumé

Since the pioneer reports of Akiyama and Terada groups on Brønsted acid organocatalysis, this field never stopped growing with the development of ingenious strategies for the activation of challenging poorly reactive substrates. The development of superacidic organocatalysts is an important way to selectively functionalize reluctant electrophiles and other approaches have also emerged such as the combination of Lewis and Brønsted acids as well as the consecutive organocatalysis and superacid activation. This concept aims to highlight these different strategies and demonstrate their complementarity.

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Chimie
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hal-04047011 , version 1 (27-03-2023)

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Bastien Michelet, Agnès Martin-Mingot, Jean Rodriguez, Sébastien Thibaudeau, Damien Bonne. Enantioselective Organocatalysis and Superacid Activation: Challenges and Opportunities. Chemistry - A European Journal, 2023, 29 (35), pp.e202300440. ⟨10.1002/chem.202300440⟩. ⟨hal-04047011⟩

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