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              <p>The local structure and density of ternary Fe-C-S liquid alloys have been studied using acombination of in situ X-ray diffraction and absorption experiments between 1 and 5 GPa and 1600–1900 K.The addition of up to 12 at% of carbon (C) to Fe-S liquid alloys does not significantly modify the structure,which is largely controlled by the perturbation to the Fe-Fe network induced by S atoms. The liquid densitydetermined from diffraction and/or absorption techniques allows us to build a non-ideal ternary mixing modelas a function of pressure, temperature, and composition in terms of the content of alloying light elements. Thecomposition of the Moon's core is addressed based on this thermodynamic model. Under the assumption ofa homogeneous liquid core proposed by two recent Moon models, the sulfur content would be 27–36 wt% or12–23 wt%, respectively, while the carbon content is mainly limited by the Fe-C-S miscibility gap, with anupper bound of 4.3 wt%. On the other hand, if the core is partially molten, the core temperature is necessarilylower than 1850 K estimated in the text, and the composition of both the inner and outer core would becontrolled by aspects of the Fe-C-S phase diagram not yet sufficiently constrained.</p>
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