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              <p>Zinc oxide (ZnO) covers a wide scope of application through its important properties, such asphotovoltaic cells [1], anti-UV coating [2], and electrode materials of capacitors [3]. Severalstudies have reported the effect of ZnO on the improvement of capacitive performance ofsupercapacitors [4-5]. However, the structural property of zinc oxide thin films is the mainreason causing the change of its electrochemical property.In this work, we have studied the effect of ZnO nanowires size on positive synergistic effect.ZnO thin films with different nanowires size were synthetized by using electrochemicalmethod. However, we managed to improve the electrochemical performance of ZnO thin filmsby creating a double scale of roughness. Microsheets and nanowires of ZnO thin films werestudied by using electrochemical methods (cyclic voltammetry and electrochemical impedancespectroscopy). Morphology of synthetized ZnO thin films was characterized by scanningelectron microscopy (SEM). Cyclic voltammetry has been carried out to study the effect of thestructural property of ZnO on the system performance. The effect of surface roughness on theelectrochemical property has been discussed.References(1) Pietruszka. R; Witkowski. B; Gieraltowska. S; Caban. P; Wachnicki. L; Zielony E;Gwozdz. K; Bieganski. P; Placzek-Popko. E; Godlewski. M; Solar Energy Materialsand Solar Cells 2015, 143, 99.(2) Ghamsari. M; Alamdari. S; Han W.; Park. H; Impact of nanostructured thin ZnO filmin ultraviolet protection. International Journal of Nanomedicine, 2017, 12, 207.(3) Naseri, M.; Fotouhi, L.; Ehsani, A.; Shiri, H. M., J. Colloid Interface Sci. 2016, 484,308.(4) Luo, Q.; Xu, P.; Qiu, Y.; Cheng, Z.; Chang, X.; Fan, H. Materials Letters 2017, 198,192.(5) Zhou, X.; Ma, L. Thin Solid Films 2015, 597, 44.</p>
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