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Article Dans Une Revue Minerals Année : 2022

Exploring Platinum Speciation with X-ray Absorption Spectroscopy under High-Energy Resolution Fluorescence Detection Mode

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Critical to interpreting platinum chemical speciation using X-ray absorption spectroscopy (XAS) is the availability of reference spectra of compounds with known Pt redox and coordination. Here we compare different techniques for Pt LIII-edge X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectral regions for a large set of Pt-O-Cl-S reference compounds of known structures. The measurements were conducted in HERFD (high-energy resolution fluorescence detection, high-resolution or HR) mode, as well as in two conventional modes such as transmission (TR) and nominal-resolution total fluorescence yield (TFY or NR). Samples analyzed here included Pt0 (TR), PtIIS (HR), PtIVS2 (TR), K2PtIICl4 (HR + TR), K2PtIVCl6 (HR + TR), PtIVO2 (HR + TR), C6H12N2O4PtII (HR + TR), and aqueous solutions of K2PtIICl4 and H2PtIVCl6 (NR + TR), as well as (NH4)2PtIV(S5)3 (HR + TR). XANES spectra in HERFD mode offer a better energy resolution than in conventional modes, allowing a more accurate identification of Pt redox state and coordination geometry. EXAFS spectra in all three modes for a given compound yield identical within errors values of Pt-neighbor interatomic distances and mean square relative displacement (MSRD, σ2) parameters. In contrast, both TR and NR spectra on the one hand and HR spectra on the other hand yield distinct amplitude reduction factor (S02) values, 0.76 ± 0.04 and 0.99 ± 0.07 (1 standard error), respectively. This study contributes to the development of an open-access XAS database SSHADE.
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hal-04001257 , version 1 (23-02-2023)

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Clément Laskar, Elena Bazarkina, Maria Kokh, Jean-Louis F Hazemann, Stéphane Foulon, et al.. Exploring Platinum Speciation with X-ray Absorption Spectroscopy under High-Energy Resolution Fluorescence Detection Mode. Minerals, 2022, 12 (12), pp.1602. ⟨10.3390/min12121602⟩. ⟨hal-04001257⟩
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